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- W2022089008 abstract "Matrix isolation infrared spectroscopy applied to the H(D)I/CH3CN system trapped in solid Ar allows identification of two forms of the 1:1 complex: a hydrogen-bonded one (C) characterized by a HI stretching frequency at 2152.5 cm−1 and a non-hydrogen-bonded one (U) with a HI mode absorbing in the monomer region. C spontaneously dissociates into U upon infrared irradiation either from the IR spectrometer source or from the laboratory thermal bath, but is regenerated by warming the matrix sample above 20 K. Extensive kinetic measurements of the disappearance (or appearance) of C have been performed in order to quantitatively discuss the role of the two parameters of the interconversion (IR radiation and temperature). On the one hand new experimental techniques have been used to improve the data, such as cooled high pass filters and heated sheets in front of the entrance windows of the cryostat. Furthermore a special effort has been made to estimate the illumination of the sample. The main conclusions drawn from the data concern the relative stability of the C/U forms, the domain of efficient radiation for the C → U conversion, the activation energy for the U → C conversion and the existence of a tunnel effect for the U → C conversion involving CH3CN:HI." @default.
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- W2022089008 date "1988-01-01" @default.
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- W2022089008 title "Infrared study of the interconversion between two forms of the CH3CN:HI complex trapped in solid argon" @default.
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- W2022089008 doi "https://doi.org/10.1016/0301-0104(88)80010-7" @default.
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