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- W2022089537 abstract "γ,δ-Unsaturated β-oxo esters can be converted into their dianions 6 by reaction with 2 equivalents of lithium diisopropylamide (LDA). Reaction of these dianions with alkyl halides leads exclusively to mono-γ-alkylation and affords the unsaturated oxo esters 9 in good yields. Reaction with carbonyl compounds similarly affords the unsaturated δ-hydroxy β-oxo esters 10. The regiospecificity of these reactions is discussed in relation to the structure of the dianionic intermediates." @default.
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- W2022089537 date "1983-01-01" @default.
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- W2022089537 title "Mono alkylation of γ,δ-unsaturated β-oxo esters via dianions. Part I" @default.
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- W2022089537 doi "https://doi.org/10.1002/recl.19831020902" @default.
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