Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022090488> ?p ?o ?g. }
- W2022090488 endingPage "2497" @default.
- W2022090488 startingPage "2497" @default.
- W2022090488 abstract "The ability of iron tricarbonyl units to control the region- and stereo-chemistry of nucleophilic addition to a neighbouring CX (X = O, N) double bond and 1,5-nucleophilic substitution via a η5-cation intermediate are described. We investigated the potential of acyclic [Fe(diene)(CO)3] complexes as chiral auxiliaries for the asymmetric synthesis of natural products. The asymmetric syntheses of (+) and (–)-frontalin, a hydroxyethylidene dipeptide isostere, a piperidine alkaloid (SS20846A), and N-Boc-O-Me-(2R,3S,5E,7E)-2-aminotetradeca- 5,7-dien-3-ol were achieved by using the stereodirecting ability and mobility of the Fe(diene)(CO)3 group. In addion, we developed an efficient method for synthesizing chiral dienal Fe(CO)3 complexes, which are versatile starting materials for the asymmetric synthesis of the biologically active natural products described above." @default.
- W2022090488 created "2016-06-24" @default.
- W2022090488 creator A5016684389 @default.
- W2022090488 creator A5040962355 @default.
- W2022090488 date "1996-01-01" @default.
- W2022090488 modified "2023-09-23" @default.
- W2022090488 title "[Fe(diene)(CO)3] complexes as a guide in stereocontrol. Applications to the asymmetric synthesis of natural products" @default.
- W2022090488 cites W1485398933 @default.
- W2022090488 cites W1970100913 @default.
- W2022090488 cites W1970318802 @default.
- W2022090488 cites W1972689269 @default.
- W2022090488 cites W1973441560 @default.
- W2022090488 cites W1982688572 @default.
- W2022090488 cites W1983548696 @default.
- W2022090488 cites W1984760913 @default.
- W2022090488 cites W1989241604 @default.
- W2022090488 cites W1990417496 @default.
- W2022090488 cites W1990485859 @default.
- W2022090488 cites W1992522713 @default.
- W2022090488 cites W1992533146 @default.
- W2022090488 cites W2000584373 @default.
- W2022090488 cites W2001951829 @default.
- W2022090488 cites W2002607311 @default.
- W2022090488 cites W2005443668 @default.
- W2022090488 cites W2007603905 @default.
- W2022090488 cites W2007933607 @default.
- W2022090488 cites W2010783155 @default.
- W2022090488 cites W2010861919 @default.
- W2022090488 cites W2013092909 @default.
- W2022090488 cites W2014503495 @default.
- W2022090488 cites W2034505109 @default.
- W2022090488 cites W2038746688 @default.
- W2022090488 cites W2040206038 @default.
- W2022090488 cites W2045047992 @default.
- W2022090488 cites W2046143876 @default.
- W2022090488 cites W2047533785 @default.
- W2022090488 cites W2057420404 @default.
- W2022090488 cites W2060147405 @default.
- W2022090488 cites W2074766741 @default.
- W2022090488 cites W2076403217 @default.
- W2022090488 cites W2081472339 @default.
- W2022090488 cites W2095923123 @default.
- W2022090488 cites W2106016877 @default.
- W2022090488 cites W2120687692 @default.
- W2022090488 cites W2132784344 @default.
- W2022090488 cites W2133805778 @default.
- W2022090488 cites W2462302392 @default.
- W2022090488 cites W2594696733 @default.
- W2022090488 cites W2949367461 @default.
- W2022090488 cites W2949721551 @default.
- W2022090488 cites W2950272163 @default.
- W2022090488 cites W2950607291 @default.
- W2022090488 cites W2951400584 @default.
- W2022090488 cites W2951581420 @default.
- W2022090488 cites W2951779184 @default.
- W2022090488 cites W2951888787 @default.
- W2022090488 cites W2952339689 @default.
- W2022090488 cites W2952533297 @default.
- W2022090488 cites W2953056810 @default.
- W2022090488 cites W2954592155 @default.
- W2022090488 cites W2527945669 @default.
- W2022090488 doi "https://doi.org/10.1039/cc9960002497" @default.
- W2022090488 hasPublicationYear "1996" @default.
- W2022090488 type Work @default.
- W2022090488 sameAs 2022090488 @default.
- W2022090488 citedByCount "33" @default.
- W2022090488 countsByYear W20220904882012 @default.
- W2022090488 countsByYear W20220904882015 @default.
- W2022090488 countsByYear W20220904882016 @default.
- W2022090488 countsByYear W20220904882017 @default.
- W2022090488 countsByYear W20220904882018 @default.
- W2022090488 countsByYear W20220904882021 @default.
- W2022090488 countsByYear W20220904882022 @default.
- W2022090488 crossrefType "journal-article" @default.
- W2022090488 hasAuthorship W2022090488A5016684389 @default.
- W2022090488 hasAuthorship W2022090488A5040962355 @default.
- W2022090488 hasConcept C135731615 @default.
- W2022090488 hasConcept C146686406 @default.
- W2022090488 hasConcept C161790260 @default.
- W2022090488 hasConcept C176933379 @default.
- W2022090488 hasConcept C178790620 @default.
- W2022090488 hasConcept C178907741 @default.
- W2022090488 hasConcept C180000673 @default.
- W2022090488 hasConcept C185592680 @default.
- W2022090488 hasConcept C20774148 @default.
- W2022090488 hasConcept C21951064 @default.
- W2022090488 hasConcept C2778733088 @default.
- W2022090488 hasConcept C2779138802 @default.
- W2022090488 hasConcept C2781462491 @default.
- W2022090488 hasConcept C515207424 @default.
- W2022090488 hasConcept C55493867 @default.
- W2022090488 hasConcept C71240020 @default.
- W2022090488 hasConceptScore W2022090488C135731615 @default.
- W2022090488 hasConceptScore W2022090488C146686406 @default.
- W2022090488 hasConceptScore W2022090488C161790260 @default.
- W2022090488 hasConceptScore W2022090488C176933379 @default.
- W2022090488 hasConceptScore W2022090488C178790620 @default.
- W2022090488 hasConceptScore W2022090488C178907741 @default.