FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022094570> ?p ?o ?g. }

• W2022094570 endingPage "1272" @default.
• W2022094570 startingPage "1264" @default.
• W2022094570 abstract "Self-association of medium-chain alcohols in n-decane solutions has been studied by infrared absorption of the fundamental OH stretching vibration. The alcohols investigated were 1-propanol, 2-methyl-1-propanol, 2-methyl-2-propanol, 1-butanol, 1-pentanol, and 1-hexanol. Infrared spectra were acquired for varying alcohol molalities, the highest concentration being 0.2 mol/kg. The spectra for each alcohol were collected in a data matrix. The bilinear multicomponent data were successfully resolved into spectra and concentration profiles by a multivariate method. The result indicates that monomers dominate the spectral variance in the low-molality region, while cyclic oligomers dominate in the upper concentration range. It further indicates that minor amounts of open-chain aggregates may be present. The monomer and cyclic tetramer appear to be the dominant species, while the amount of open-chain aggregates was negligible even in the low-molality region. The equilibrium constants for the monomer–tetramer association reactions ( K 1–4 ) were calculated by a least-squares method. The calculated values for the equilibrium constants, based on the molality, range from 138 to 106 for the linear alcohol molecules. The result shows that 1-butanol, 1-pentanol, and 1-hexanol have similar constants, while 1-propanol displays a markedly higher value. The equilibrium constants obtained for 2-methyl-1-propanol and 2-methyl-2-propanol were 77 and 39, respectively. The considerably lower values for the branched alcohol molecules indicate that steric interaction between the chain prevents self-association into larger aggregates." @default.
• W2022094570 created "2016-06-24" @default.
• W2022094570 creator A5015628501 @default.
• W2022094570 creator A5016029392 @default.
• W2022094570 creator A5026253409 @default.
• W2022094570 creator A5046348508 @default.
• W2022094570 date "1996-10-01" @default.
• W2022094570 modified "2023-10-03" @default.
• W2022094570 title "Self-Association of Medium-Chain Alcohols in <i>n</i>-Decane Solutions" @default.
• W2022094570 cites W1514803271 @default.
• W2022094570 cites W1969108158 @default.
• W2022094570 cites W1969335435 @default.
• W2022094570 cites W1971554669 @default.
• W2022094570 cites W1972326413 @default.
• W2022094570 cites W1972496200 @default.
• W2022094570 cites W1974376260 @default.
• W2022094570 cites W1980466954 @default.
• W2022094570 cites W1992178940 @default.
• W2022094570 cites W1993195479 @default.
• W2022094570 cites W2021865183 @default.
• W2022094570 cites W2022704546 @default.
• W2022094570 cites W2023868188 @default.
• W2022094570 cites W2029420020 @default.
• W2022094570 cites W2030149507 @default.
• W2022094570 cites W2047342150 @default.
• W2022094570 cites W2057635418 @default.
• W2022094570 cites W2066988013 @default.
• W2022094570 cites W2075102933 @default.
• W2022094570 cites W2075255780 @default.
• W2022094570 cites W2085424994 @default.
• W2022094570 cites W2087658534 @default.
• W2022094570 cites W2089468765 @default.
• W2022094570 doi "https://doi.org/10.1366/0003702963904854" @default.
• W2022094570 hasPublicationYear "1996" @default.
• W2022094570 type Work @default.
• W2022094570 sameAs 2022094570 @default.
• W2022094570 citedByCount "51" @default.
• W2022094570 countsByYear W20220945702012 @default.
• W2022094570 countsByYear W20220945702013 @default.
• W2022094570 countsByYear W20220945702014 @default.
• W2022094570 countsByYear W20220945702015 @default.
• W2022094570 countsByYear W20220945702016 @default.
• W2022094570 countsByYear W20220945702017 @default.
• W2022094570 countsByYear W20220945702021 @default.
• W2022094570 countsByYear W20220945702023 @default.
• W2022094570 crossrefType "journal-article" @default.
• W2022094570 hasAuthorship W2022094570A5015628501 @default.
• W2022094570 hasAuthorship W2022094570A5016029392 @default.
• W2022094570 hasAuthorship W2022094570A5026253409 @default.
• W2022094570 hasAuthorship W2022094570A5046348508 @default.
• W2022094570 hasConcept C10710636 @default.
• W2022094570 hasConcept C113196181 @default.
• W2022094570 hasConcept C147789679 @default.
• W2022094570 hasConcept C153642686 @default.
• W2022094570 hasConcept C166940927 @default.
• W2022094570 hasConcept C16946580 @default.
• W2022094570 hasConcept C178790620 @default.
• W2022094570 hasConcept C181199279 @default.
• W2022094570 hasConcept C184651966 @default.
• W2022094570 hasConcept C185592680 @default.
• W2022094570 hasConcept C2776981874 @default.
• W2022094570 hasConcept C2778886173 @default.
• W2022094570 hasConcept C2781066024 @default.
• W2022094570 hasConcept C32909587 @default.
• W2022094570 hasConcept C521977710 @default.
• W2022094570 hasConceptScore W2022094570C10710636 @default.
• W2022094570 hasConceptScore W2022094570C113196181 @default.
• W2022094570 hasConceptScore W2022094570C147789679 @default.
• W2022094570 hasConceptScore W2022094570C153642686 @default.
• W2022094570 hasConceptScore W2022094570C166940927 @default.
• W2022094570 hasConceptScore W2022094570C16946580 @default.
• W2022094570 hasConceptScore W2022094570C178790620 @default.
• W2022094570 hasConceptScore W2022094570C181199279 @default.
• W2022094570 hasConceptScore W2022094570C184651966 @default.
• W2022094570 hasConceptScore W2022094570C185592680 @default.
• W2022094570 hasConceptScore W2022094570C2776981874 @default.
• W2022094570 hasConceptScore W2022094570C2778886173 @default.
• W2022094570 hasConceptScore W2022094570C2781066024 @default.
• W2022094570 hasConceptScore W2022094570C32909587 @default.
• W2022094570 hasConceptScore W2022094570C521977710 @default.
• W2022094570 hasIssue "10" @default.
• W2022094570 hasLocation W20220945701 @default.
• W2022094570 hasOpenAccess W2022094570 @default.
• W2022094570 hasPrimaryLocation W20220945701 @default.
• W2022094570 hasRelatedWork W1994374753 @default.
• W2022094570 hasRelatedWork W2003774662 @default.
• W2022094570 hasRelatedWork W2022094570 @default.
• W2022094570 hasRelatedWork W2049225943 @default.
• W2022094570 hasRelatedWork W2055546481 @default.
• W2022094570 hasRelatedWork W2061255768 @default.
• W2022094570 hasRelatedWork W2078632160 @default.
• W2022094570 hasRelatedWork W2095216774 @default.
• W2022094570 hasRelatedWork W2097622231 @default.
• W2022094570 hasRelatedWork W2392092941 @default.
• W2022094570 hasVolume "50" @default.
• W2022094570 isParatext "false" @default.
• W2022094570 isRetracted "false" @default.
• W2022094570 magId "2022094570" @default.

• next