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• W2022097495 endingPage "2044" @default.
• W2022097495 startingPage "2034" @default.
• W2022097495 abstract "Reaction rate constants for nine site-specific hydrogen atom (H) abstraction by hydroxyl radicals (OH) have been determined using experimental measurements of the rate constants of Alkane + OH ? Products reactions. Seven secondary (S20, S21, S22, S30, S31, S32, and S33) and two tertiary (T100 and T101) site-specific rate constants, where the subscripts refer to the number of carbon atoms (C) connected to the next–nearest–neighbor (N–N–N) C atom, were obtained for a wide temperature range (250– 1450 K). This was done by measuring the reaction rate constants for H abstraction by OH from a series of carefully selected large branched alkanes. The rate constant of OH with four different alkanes, namely 2,2-dimethyl-pentane, 2,4-dimethyl-pentane, 2,2,4-trimethyl-pentane (iso-octane), and 2,2,4,4-tetramethyl-pentane were measured at high temperatures (822–1367 K) using a shock tube and OH absorption diagnostic. Hydroxyl radicals were detected using the narrow-line-width ring-dye laser absorption of the" @default.
• W2022097495 created "2016-06-24" @default.
• W2022097495 creator A5017998380 @default.
• W2022097495 creator A5051525030 @default.
• W2022097495 date "2015-05-01" @default.
• W2022097495 modified "2023-09-26" @default.
• W2022097495 title "Site-specific reaction rate constant measurements for various secondary and tertiary H-abstraction by OH radicals" @default.
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• W2022097495 doi "https://doi.org/10.1016/j.combustflame.2015.01.001" @default.
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