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- W2022101134 abstract "Recent high-resolution x-ray investigations of the smectic-$A$ (SmA) phase near the nematic-to-SmA transition provide information about the critical behavior of the linear thermal expansion coefficient ${ensuremath{alpha}}_{ensuremath{Vert}}$ parallel to the director. Combining such data with available volume thermal expansion ${ensuremath{alpha}}_{V}$ data yields the in-plane linear expansion coefficient ${ensuremath{alpha}}_{ensuremath{perp}}$. The critical behaviors of ${ensuremath{alpha}}_{ensuremath{Vert}}$ and ${ensuremath{alpha}}_{ensuremath{perp}}$ are the same as those for ${ensuremath{alpha}}_{V}$ and the heat capacity ${C}_{p}$. However, for any given liquid crystal, ${ensuremath{alpha}}_{ensuremath{Vert}}(mathrm{crit})$ and ${ensuremath{alpha}}_{ensuremath{perp}}(mathrm{crit})$ differ in sign. Furthermore, the quantity ${ensuremath{alpha}}_{ensuremath{Vert}}(mathrm{crit})$ is positive for ${mathrm{SmA}}_{d}$ partial bilayer smectics, while it is negative for nonpolar ${mathrm{SmA}}_{m}$ monomeric smectics. This feature is discussed in terms of the molecular structural aspects of these smectic phases." @default.
- W2022101134 created "2016-06-24" @default.
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- W2022101134 date "2004-10-21" @default.
- W2022101134 modified "2023-09-27" @default.
- W2022101134 title "Critical linear thermal expansion in the smectic-<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi>A</mml:mi></mml:math>phase near the nematic-smectic phase transition" @default.
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- W2022101134 doi "https://doi.org/10.1103/physreve.70.041703" @default.
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