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- W2022104106 abstract "The infrared spectra of azulene and its isotopic modifications d2(1,3), d6(2,4,5,6,7,8) and d8 have been measured between 4000 and 280 cm−1 polarized and unpolarized crystal spectra, in addition to solution spectra, were investigated. Based on these spectra, vibrational assignments are discussed for all four isotopic species. For the A1 and B1 fundamentals the assignments suggested are complete and satisfactorily obey the sum and product rules. An assignment is also proposed for the B2 fundamentals, which is considered to be complete for the light molecule d0, but includes two estimated fundamentals for the deuterated species in the far-infrared region. Finally, a tentative and incomplete assignment for the A2 fundamentals is given, as well as a plausible interpretation of the remaining parts of the infrared spectra in terms of combination tones." @default.
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- W2022104106 date "1963-09-01" @default.
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- W2022104106 title "Infrared spectra of four isotopic species of azulene" @default.
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- W2022104106 doi "https://doi.org/10.1016/0371-1951(63)80012-0" @default.
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