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- W2022104112 abstract "Abstract We found new synthetic routes to obtain 1-D quaternary thiophosphate compounds and a 0-D molecular complex containing a Nb 2 S 4 core from a 2-D ternary thiophosphate, Nb 4 P 2 S 21 . When Nb 4 P 2 S 21 was reacted with alkali metal halides ( A Cl; A =Na, K, Rb, Cs) or TlCl at 500–700 °C, the –S–S–S– bridges in 2-D Nb 2 PS 10 -S-S 10 PNb 2 were excised to form a 1-D chain, and cations were inserted between the chains to form A Nb 2 PS 10 ( A =Na, K, Rb, Cs, Tl). We also found that thallium chloride (TlCl) is an excellent reagent for further excision, and it substitutes chloride ligands for the sulfur ligands of 2-D Nb 4 P 2 S 21 to form the molecular complex Tl 5 [Nb 2 S 4 Cl 8 ]Cl. Crystal data for TlNb 2 PS 10 : monoclinic, Pn , a =6.9452(11) A, b =7.3761(12) A, 12.873(2) A, β =104.472(3)°, and Z =2. Crystal data for Tl 5 [Nb 2 S 4 Cl 8 ]Cl: orthorhombic, Immm , a =7.001(5) A, b =9.509(7) A, c =15.546(11) A, and Z =2." @default.
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- W2022104112 date "2008-08-01" @default.
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- W2022104112 title "Dimensional reductions from 2-D Nb4P2S21 to 1-D ANb2PS10 (A=Na, K, Rb, Cs, Tl) and to 0-D Tl5[Nb2S4Cl8]Cl using halide molten salts" @default.
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- W2022104112 doi "https://doi.org/10.1016/j.jssc.2008.03.040" @default.
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