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- W2022104182 abstract "A new stannosilicate Cs2SnSi3O9 has been synthesized and characterized by single-crystal X-ray diffraction and solid-state NMR spectroscopy. It crystallizes in the orthorhombic space group P212121 (No. 19) with a=7.9612(7)Å, b=10.3444(9)Å, c=11.780(1)Å, V=970.1(3)Å3, and Z=4 with R1=0.0189. The structure consists of helical silicate chains with a period of six tetrahedra which are connected by SnO6 octahedra to form a 3D framework containing 6-ring and 7-ring channels where the Cs+ cations reside. This work is one of the few studies concerning the synthesis of stannosilicates under high-temperature and high-pressure hydrothermal conditions." @default.
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- W2022104182 date "2005-04-01" @default.
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- W2022104182 title "High-temperature, high-pressure hydrothermal synthesis and characterization of a new framework stannosilicate: Cs2SnSi3O9" @default.
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- W2022104182 doi "https://doi.org/10.1016/j.jssc.2004.12.002" @default.
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