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- W2022104506 abstract "The ν2 and 2ν6 infrared bands of 28SiH3D have been recorded between 1450 and 1710 cm−1 with 0.005 cm−1 apodized spectral resolution using a Fourier transform spectrometer. Line assignments were made from J = 0 to 25 and K = 0 to 15 for the ν2 band, from J = 0 to 20 and K = 0 to 13 for the 2ν60 band, and from J = 0 to 20 and K = 0 to 8 for the 2ν62 band. Very strong perturbations were observed in all three components of the triad system, including l-type interactions between 2ν60 and 2ν62 and Fermi interactions between ν2 and 2ν6. Observed transitions were fit using ground state constants, derived from ground state combination differences, and upper state energy levels, obtained by diagonalizing an energy matrix including Fermi resonance terms between v2 = 1 and v6 = 2. Molecular coefficients and their method of determination are reported." @default.
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- W2022104506 date "1988-03-01" @default.
- W2022104506 modified "2023-09-30" @default.
- W2022104506 title "High-resolution infrared spectrum of 28SiH3D from 1450 to 1710 cm−1" @default.
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- W2022104506 doi "https://doi.org/10.1016/0022-2852(88)90213-5" @default.
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