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• W2022105623 endingPage "1803" @default.
• W2022105623 startingPage "1798" @default.
• W2022105623 abstract "Thermal analysis, impedance spectroscopy, NMR and Raman spectroscopy have been used to investigate the plastic crystal dimethylpyrrolidinium thiocyanate in order to gain further insight into the properties of organic ionic plastic crystals. This compound has a solid–solid phase transition at 82 °C, and melts at 122 °C. A step increase in conductivity of about one order of magnitude is observed at the phase transition, followed by a decrease in activation energy for conduction. A large entropy gain occurs at the II → I transition, and 1H NMR linewidth measurements together with second moment calculations showed that the dimethylpyrrolidinium cation goes from a static state, to full isotropic tumbling. Raman measurements confirm that the cation as well as the anion exhibit increased rotational mobility when entering phase I." @default.
• W2022105623 created "2016-06-24" @default.
• W2022105623 creator A5088958176 @default.
• W2022105623 date "2008-02-15" @default.
• W2022105623 modified "2023-10-14" @default.
• W2022105623 title "Rotational and translational mobility of a highly plastic salt: Dimethylpyrrolidinium thiocyanate" @default.
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• W2022105623 doi "https://doi.org/10.1016/j.ssi.2007.12.017" @default.
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