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- W2022107946 abstract "The influence of rotation on the intramolecular dynamics of hydrogen peroxide is studied using classical trajectories. Rotation-vibration interactions cause a substantial enhancement in vibrational energy flow. The strongest interactions appear to be between rotation and the low frequency torsional mode. The vibrational energy transfer out of the fifth OH overtone in rotationally excited (0.2 eV of rotational energy, corresponding to 1500 K) H2O2 is about twice that of non-rotating H2O2 for the 3.25 ps time period for which the trajectories were followed. The rate coefficient for unimolecular dissociation of rotating H2O2 is 2.5 times that for non-rotating H2O2." @default.
- W2022107946 created "2016-06-24" @default.
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- W2022107946 date "1988-12-01" @default.
- W2022107946 modified "2023-10-13" @default.
- W2022107946 title "Influence of rotation on the intramolecular dynamics of hydrogen peroxide" @default.
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- W2022107946 doi "https://doi.org/10.1016/0009-2614(88)85220-5" @default.
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