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- W2022109402 abstract "The ternary solubility phase diagrams of the N-methylephedrine species in two chiral solvents, (S)-ethyl lactate and (2R,3R)-diethyl tartrate, have been studied. Solubility measurements were performed for enantiomeric compositions and temperatures ranging from 1:1 mixtures to the pure enantiomer and from (273 to 313) K. Predicted ideal solubility curves of the N-methylephedrine species in both solvents revealed deviations from experimental data. The nonrandom two-liquid model was applied to quantify and parametrize these nonidealities and nonideal heterochiral interactions among the enantiomers by means of corresponding activity coefficients. The solvent−solute interactions were interpreted as nonchiral specific, since no asymmetry in the chiral systems were found. The selection of an appropriate solvent for a crystallization-based enantioseparation based on the shape of solubility isotherms is discussed." @default.
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- W2022109402 date "2009-10-16" @default.
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- W2022109402 title "Solid−Liquid Phase Equilibria of <i>N</i>-Methylephedrine Enantiomers in Two Chiral Solvents" @default.
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- W2022109402 doi "https://doi.org/10.1021/je900572c" @default.
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