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• W2022110207 abstract "Abstract The structure of the new compound [Mo(η 5 -C 5 H 5 ) 2 (2-NHNC 5 H 4 )][PF 6 ] ( 1 ) has been determined. The crystals are orthorhombic, space group Pca 2 1 with a 20.807(1), b 8.0030(8), c 10.056(3) A, V 1674.5 A 3 , Z = 4. The structure of [Mo(η 5 -C 5 H 5 ) 2 (2-ONC 5 H 4 )][PF 6 ] ( 2 ) has also been determined. The crystals are orthorhombic, space group Pnma with a 12.727(3), b 10.174(2), c 12.918(1) A, V 1672.8 A 3 , Z = 4. The structures were solved by Patterson and difference electron density syntheses and refined by least-squares to R of 0.028 for 1287 reflections for 1 and 0.059 for 1178 reflections for 2 . Although not isostructural the two cationic complexes have equivalent geometries with the normal bent bismetallocene structure. For 1 the MoN bond lengths are 2.160(8) and 2.142(9) A, with a NMoN bond angle of 59.8(3)°, whereas for 2 MoO is 2.142(10), MoN is 2.138(11) A, the NMoO angle is 61.2(4)°. These parameters are discussed and compared with the corresponding data for similar biscyclopentadienyl complexes of molybdenum(IV). Extended Huckel molecular orbital calculations have been carried out to throw light on the nature of the bonding between the metal and the bidentate ligand." @default.
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• W2022110207 date "1987-02-01" @default.
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• W2022110207 title "Molecular structure of two dicyclopentadienylmolybdenum derivatives containing a four-membered ring [Mo(η5-C5H5)2(2-NHNC5H4)][PF6] and [Mo(η5C5H5)2(2-ONC5H4)][PF6]" @default.
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• W2022110207 doi "https://doi.org/10.1016/0022-328x(87)85079-9" @default.
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