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• W2022110917 abstract "SN2-selective Grignard coupling with primary allylic diphenylphosphates was successfully achieved using Ni or Fe catalyst. In sharp contrast, a catalytic amount of CuCN·2LiCl promoted a SN2′-selective coupling reaction. In the presence of the copper catalyst, stereochemically homogeneous γ- disubstituted allyl Grignard reagents reacted at the less substituted allylic terminus (α-position) with an allylic diphenylphosphate selectively without losing the double bond geometry." @default.
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• W2022110917 date "1994-01-01" @default.
• W2022110917 modified "2023-10-16" @default.
• W2022110917 title "Transition metal-catalyzed substitution reaction of allylic phosphates with Grignard reagents" @default.
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• W2022110917 doi "https://doi.org/10.1016/s0040-4020(01)90454-5" @default.
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