FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022113368> ?p ?o ?g. }

• W2022113368 endingPage "3278" @default.
• W2022113368 startingPage "3268" @default.
• W2022113368 abstract "A series of dinuclear complexes, (mu-SRS)Fe(2)(CO)(6) (R = -CH(2)CH(2)-, -CH(2)CH(2)CH(2)-, -CH(2)-C(6)H(4)-CH(2)-; edt, pdt, and o-xyldt, respectively) has been examined for specific characteristics that might relate to structural similarity with the active site of Fe-only hydrogenases. Variable-temperature proton NMR studies display the fluxionality of the iron-dithiocyclohexane unit in (mu-pdt)Fe(2)(CO)(6) while in the (mu-o-xyldt)Fe(2)(CO)(6) compound, the bridge is fixed. Temperature-dependent (13)C NMR spectral studies establish intramolecular CO site exchange localized on discrete Fe(CO)(3) units in all complexes, which is influenced by steric effects of the mu-SRS unit. Kinetic studies of intermolecular CO/CN(-) ligand-exchange reactions establish associative or I(a) mechanisms in sequential steps to form the dicyano dianion, (mu-SRS)[Fe(CO)(2)(CN)](2)(=) with 100% selectivity. Theoretical calculations (DFT) of transition states in the intramolecular site-exchange processes lead to a rationale for the interesting cooperativity in the CN(-)/CO intermolecular ligand-exchange process. The hinge motion of the three light atom S-to-S bridge is related to a possible heterolytic H(2) activation/production process in the enzyme." @default.
• W2022113368 created "2016-06-24" @default.
• W2022113368 creator A5031939982 @default.
• W2022113368 creator A5050058500 @default.
• W2022113368 creator A5065780097 @default.
• W2022113368 creator A5088587202 @default.
• W2022113368 date "2001-03-17" @default.
• W2022113368 modified "2023-10-17" @default.
• W2022113368 title "Coordination Sphere Flexibility of Active-Site Models for Fe-Only Hydrogenase: Studies in Intra- and Intermolecular Diatomic Ligand Exchange" @default.
• W2022113368 cites W1966177471 @default.
• W2022113368 cites W1966182479 @default.
• W2022113368 cites W1966252600 @default.
• W2022113368 cites W1967729189 @default.
• W2022113368 cites W1967818673 @default.
• W2022113368 cites W1971396352 @default.
• W2022113368 cites W1976434962 @default.
• W2022113368 cites W1977683799 @default.
• W2022113368 cites W1980423322 @default.
• W2022113368 cites W1980908623 @default.
• W2022113368 cites W1982356449 @default.
• W2022113368 cites W1983730749 @default.
• W2022113368 cites W1984614201 @default.
• W2022113368 cites W1987969019 @default.
• W2022113368 cites W2004686031 @default.
• W2022113368 cites W2006561732 @default.
• W2022113368 cites W2009162331 @default.
• W2022113368 cites W2011047335 @default.
• W2022113368 cites W2015900409 @default.
• W2022113368 cites W2023271753 @default.
• W2022113368 cites W2026255826 @default.
• W2022113368 cites W2037281145 @default.
• W2022113368 cites W2038690593 @default.
• W2022113368 cites W2044490585 @default.
• W2022113368 cites W2048179590 @default.
• W2022113368 cites W2050244287 @default.
• W2022113368 cites W2055281567 @default.
• W2022113368 cites W2055609338 @default.
• W2022113368 cites W2061732974 @default.
• W2022113368 cites W2062340785 @default.
• W2022113368 cites W2062417798 @default.
• W2022113368 cites W2068617439 @default.
• W2022113368 cites W2071183489 @default.
• W2022113368 cites W2072454801 @default.
• W2022113368 cites W2080075262 @default.
• W2022113368 cites W2082712943 @default.
• W2022113368 cites W2086957099 @default.
• W2022113368 cites W2104796556 @default.
• W2022113368 cites W2112345360 @default.
• W2022113368 cites W2122235373 @default.
• W2022113368 cites W2143766385 @default.
• W2022113368 cites W2143981217 @default.
• W2022113368 cites W2149590280 @default.
• W2022113368 cites W2153941811 @default.
• W2022113368 cites W2322900141 @default.
• W2022113368 cites W252918209 @default.
• W2022113368 cites W2949781292 @default.
• W2022113368 cites W2953143610 @default.
• W2022113368 cites W3005370881 @default.
• W2022113368 cites W3024709322 @default.
• W2022113368 cites W3138078448 @default.
• W2022113368 doi "https://doi.org/10.1021/ja003147z" @default.
• W2022113368 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11457062" @default.
• W2022113368 hasPublicationYear "2001" @default.
• W2022113368 type Work @default.
• W2022113368 sameAs 2022113368 @default.
• W2022113368 citedByCount "254" @default.
• W2022113368 countsByYear W20221133682012 @default.
• W2022113368 countsByYear W20221133682013 @default.
• W2022113368 countsByYear W20221133682014 @default.
• W2022113368 countsByYear W20221133682015 @default.
• W2022113368 countsByYear W20221133682016 @default.
• W2022113368 countsByYear W20221133682017 @default.
• W2022113368 countsByYear W20221133682018 @default.
• W2022113368 countsByYear W20221133682019 @default.
• W2022113368 countsByYear W20221133682020 @default.
• W2022113368 countsByYear W20221133682021 @default.
• W2022113368 countsByYear W20221133682022 @default.
• W2022113368 countsByYear W20221133682023 @default.
• W2022113368 crossrefType "journal-article" @default.
• W2022113368 hasAuthorship W2022113368A5031939982 @default.
• W2022113368 hasAuthorship W2022113368A5050058500 @default.
• W2022113368 hasAuthorship W2022113368A5065780097 @default.
• W2022113368 hasAuthorship W2022113368A5088587202 @default.
• W2022113368 hasConcept C11111787 @default.
• W2022113368 hasConcept C111592845 @default.
• W2022113368 hasConcept C115624301 @default.
• W2022113368 hasConcept C116569031 @default.
• W2022113368 hasConcept C161790260 @default.
• W2022113368 hasConcept C166014724 @default.
• W2022113368 hasConcept C166950319 @default.
• W2022113368 hasConcept C170493617 @default.
• W2022113368 hasConcept C178790620 @default.
• W2022113368 hasConcept C185592680 @default.
• W2022113368 hasConcept C201194858 @default.
• W2022113368 hasConcept C32909587 @default.
• W2022113368 hasConcept C41183919 @default.
• W2022113368 hasConcept C55493867 @default.
• W2022113368 hasConcept C71240020 @default.

• next