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• W2022120595 endingPage "290" @default.
• W2022120595 startingPage "276" @default.
• W2022120595 abstract "A compilation of experimental values of the infinite dilution partial molar Gibbs energy, enthalpy, and heat capacity of hydration, together with partial molar volumes in water at 298.15 K and 0.1 MPa is presented for aliphatic monoethers, diethers, and polyethers. These data are treated in the framework of the first- and second-order group additivity methods. However, third- and higher-order effects (i.e., interactions expressed beyond the nearest neighbors) are clearly present in aqueous ethers. The effects can be accounted for by the introduction of a number of corrections. For the second-order group contribution method, numerical values are determined for the following groups: C−(C)2(H)(O)ether, C−(C)3(O)ether, O−(C)2, C−(H)2(O)2, C−(C)(O)2(H), and corrections: a “ethoxyalkane” correction, {CH3−CH2−O−CH2}, and a “diether” correction, {O−(CH2)2−O}. For the first-order group contribution method, in addition to the “ether” O group, a large number of corrections appears to be necessary for accurate reproduction of the compiled data: “ethoxyalkane”, and “diether”, corrections, two “acetal”, {O−CH2−O} and {O−CH(CH3)-O}, corrections, as well as “tertiary”, {Ctert-O}, and “ternary”, {HCtern-O}, corrections, applied to monoethers that have direct contacts of tertiary and ternary carbon atom with oxygen." @default.
• W2022120595 created "2016-06-24" @default.
• W2022120595 creator A5007970581 @default.
• W2022120595 creator A5061173644 @default.
• W2022120595 creator A5088632111 @default.
• W2022120595 date "2005-12-02" @default.
• W2022120595 modified "2023-10-15" @default.
• W2022120595 title "Group Contribution Values for the Thermodynamic Functions of Hydration at 298.15 K, 0.1 MPa. 3. Aliphatic Monoethers, Diethers, and Polyethers" @default.
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