Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022121535> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W2022121535 endingPage "1754" @default.
- W2022121535 startingPage "1747" @default.
- W2022121535 abstract "The cocyclization reaction of pentacarbonyl(beta-amino-1-ethoxyalkenylidene)chromium complexes 1 with alkynes has been studied with respect to the effects of substituents, solvents, ligand additives, and reagent concentrations upon the product distribution. This reaction proceeds either as a formal [2 + 2 + 1] cycloaddition to give 5-(1'-dialkylaminoalkylidene)-4-ethoxycyclopent-2-enones 8 or a formal [3 + 2] cycloaddition to give 5-dialkylamino-3-ethoxy-1,3-cyclopentadienes 9. A working hypothesis for the mechanism of this reaction is proposed on the basis of that previously determined for the Dötz reaction. The effects of the aforementioned parameters upon the product distribution of this current reaction are explained in terms of this model. A pronounced ligand-induced allochemical effect has been observed. Conditions for the selective preparation of both classes of cycloadducts 8 and 9 have been determined." @default.
- W2022121535 created "2016-06-24" @default.
- W2022121535 creator A5027519450 @default.
- W2022121535 creator A5031339750 @default.
- W2022121535 creator A5056358838 @default.
- W2022121535 creator A5063128550 @default.
- W2022121535 date "2001-02-07" @default.
- W2022121535 modified "2023-10-16" @default.
- W2022121535 title "Highly Functionalized Five-Membered Carbocycles from (3-Dialkylamino-1-ethoxyalkenylidene)pentacarbonylchromium Complexes and Alkynes: The Effects of Substituents, Solvents, Ligand Additives, and Reagent Concentrations on the Product Distribution" @default.
- W2022121535 cites W1967984284 @default.
- W2022121535 cites W196915156 @default.
- W2022121535 cites W1990190382 @default.
- W2022121535 cites W1993696506 @default.
- W2022121535 cites W2001726531 @default.
- W2022121535 cites W2011146708 @default.
- W2022121535 cites W2040230919 @default.
- W2022121535 cites W2053813547 @default.
- W2022121535 cites W2062338380 @default.
- W2022121535 cites W2072381123 @default.
- W2022121535 cites W2095476334 @default.
- W2022121535 cites W2950174642 @default.
- W2022121535 cites W2950718781 @default.
- W2022121535 cites W2950822577 @default.
- W2022121535 cites W2951765901 @default.
- W2022121535 cites W2952159421 @default.
- W2022121535 doi "https://doi.org/10.1021/jo005708a" @default.
- W2022121535 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11262122" @default.
- W2022121535 hasPublicationYear "2001" @default.
- W2022121535 type Work @default.
- W2022121535 sameAs 2022121535 @default.
- W2022121535 citedByCount "25" @default.
- W2022121535 countsByYear W20221215352013 @default.
- W2022121535 countsByYear W20221215352014 @default.
- W2022121535 countsByYear W20221215352017 @default.
- W2022121535 crossrefType "journal-article" @default.
- W2022121535 hasAuthorship W2022121535A5027519450 @default.
- W2022121535 hasAuthorship W2022121535A5031339750 @default.
- W2022121535 hasAuthorship W2022121535A5056358838 @default.
- W2022121535 hasAuthorship W2022121535A5063128550 @default.
- W2022121535 hasConcept C110121322 @default.
- W2022121535 hasConcept C116569031 @default.
- W2022121535 hasConcept C134306372 @default.
- W2022121535 hasConcept C155647269 @default.
- W2022121535 hasConcept C161790260 @default.
- W2022121535 hasConcept C170493617 @default.
- W2022121535 hasConcept C17112743 @default.
- W2022121535 hasConcept C178790620 @default.
- W2022121535 hasConcept C185592680 @default.
- W2022121535 hasConcept C2779664164 @default.
- W2022121535 hasConcept C2780263894 @default.
- W2022121535 hasConcept C33923547 @default.
- W2022121535 hasConcept C40875361 @default.
- W2022121535 hasConcept C511782168 @default.
- W2022121535 hasConcept C55493867 @default.
- W2022121535 hasConcept C65024703 @default.
- W2022121535 hasConcept C71240020 @default.
- W2022121535 hasConcept C90150868 @default.
- W2022121535 hasConceptScore W2022121535C110121322 @default.
- W2022121535 hasConceptScore W2022121535C116569031 @default.
- W2022121535 hasConceptScore W2022121535C134306372 @default.
- W2022121535 hasConceptScore W2022121535C155647269 @default.
- W2022121535 hasConceptScore W2022121535C161790260 @default.
- W2022121535 hasConceptScore W2022121535C170493617 @default.
- W2022121535 hasConceptScore W2022121535C17112743 @default.
- W2022121535 hasConceptScore W2022121535C178790620 @default.
- W2022121535 hasConceptScore W2022121535C185592680 @default.
- W2022121535 hasConceptScore W2022121535C2779664164 @default.
- W2022121535 hasConceptScore W2022121535C2780263894 @default.
- W2022121535 hasConceptScore W2022121535C33923547 @default.
- W2022121535 hasConceptScore W2022121535C40875361 @default.
- W2022121535 hasConceptScore W2022121535C511782168 @default.
- W2022121535 hasConceptScore W2022121535C55493867 @default.
- W2022121535 hasConceptScore W2022121535C65024703 @default.
- W2022121535 hasConceptScore W2022121535C71240020 @default.
- W2022121535 hasConceptScore W2022121535C90150868 @default.
- W2022121535 hasIssue "5" @default.
- W2022121535 hasLocation W20221215351 @default.
- W2022121535 hasLocation W20221215352 @default.
- W2022121535 hasOpenAccess W2022121535 @default.
- W2022121535 hasPrimaryLocation W20221215351 @default.
- W2022121535 hasRelatedWork W2089879623 @default.
- W2022121535 hasRelatedWork W2111124698 @default.
- W2022121535 hasRelatedWork W2321903118 @default.
- W2022121535 hasRelatedWork W2389438109 @default.
- W2022121535 hasRelatedWork W2808280190 @default.
- W2022121535 hasRelatedWork W3202309119 @default.
- W2022121535 hasRelatedWork W3203723238 @default.
- W2022121535 hasRelatedWork W4210992829 @default.
- W2022121535 hasRelatedWork W4211051702 @default.
- W2022121535 hasRelatedWork W4211090705 @default.
- W2022121535 hasVolume "66" @default.
- W2022121535 isParatext "false" @default.
- W2022121535 isRetracted "false" @default.
- W2022121535 magId "2022121535" @default.
- W2022121535 workType "article" @default.