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- W2022122431 abstract "(Triphenylstannyl)methyllithium (1a) sowie analoge Trialkylstannyl-Verbindungen (1b, c) wurden durch Halogen-Lithium-Austausch aus 3a–c synthetisiert. Die erzielten hohen Ausbeuten zeigen, daß Stannylgruppen ein carbanionisches Zentrum stabilisieren. 1a reagiert mit Aldehyden und Ketonen zu β-Hydroxystannanen 5, die zur Olefinbildung neigen. New Reagents, XX. (Triphenylstannyl)methyllithium and Analogous Trialkylstannyl Compounds, Synthesis and Reactions (Triphenylstannyl)methyllithium (1a) and analogous trialkylstannyl compounds (1b, c) were synthesized by halogen-lithium exchange reactions from 3a–c. As shown by high yields, stannyl groups are capable of stabilizing a carbanionic centre. 1a reacts with aldehydes and ketones to give β-hydroxystannanes 5 which tend to form olefins." @default.
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- W2022122431 date "1982-05-01" @default.
- W2022122431 modified "2023-10-09" @default.
- W2022122431 title "Neue Reagenzien, XX. (Triphenylstannyl)methyllithium und analoge Trialkylstannyl‐Verbindungen, Synthese und Reaktionen" @default.
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- W2022122431 doi "https://doi.org/10.1002/cber.19821150514" @default.
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