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- W2022122496 abstract "In this paper, we have reported a novel hierarchical nanostructure made of vertically ordered Ni3Si2/Si nanorod arrays to moderate the notorious pulverization and capacity decay usually occurring in the silicon used as the anode materials in Li-ion batteries. During the lithiation and delithiation process, the amorphous Si (a-Si) layer acts as an active material and participates in the processes, whereas the Ni3Si2 nanorod arrays work as a mechanically stable supporter and fast charge transport pathway. In addition, they can afford sufficient interspace for expansion/contraction upon lithium insertion/extraction. These Ni3Si2/Si nanorod arrays anodes exhibit excellent cycling performance at high current rates of 1 C (4.2 A g−1), 2 C (8.4 A g−1), and 4 C (16.8 A g−1), respectively. A high and steady discharge capacity of over 2184 mA h g−1 can be achieved after 50 cycles with a high initial coulombic efficiency of 86.7%. The synthesis approach is simple, efficient and rich-yielding, probably providing a new strategy for the application of silicon-based anode materials with enhanced performance." @default.
- W2022122496 created "2016-06-24" @default.
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- W2022122496 date "2012-01-01" @default.
- W2022122496 modified "2023-09-24" @default.
- W2022122496 title "Vertically ordered Ni3Si2/Si nanorod arrays as anode materials for high-performance Li-ion batteries" @default.
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- W2022122496 doi "https://doi.org/10.1039/c2nr31045g" @default.
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