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• W2022127834 abstract "The substitution of chloro or bromo groups in tetracene gives rise to the change of crystal structure, having a substantial effect on carrier transport. Halogenated tetracene derivatives were synthesized and grown into single crystals. Monosubstituted 5-bromo- and 5-chlorotetracenes have the herringbone-type structure, while 5,11-dichlorotetracene has the slipped π stacking structure. Mobility of 5,11-dichlorotetracene was measured to be as high as 1.6 cm2/V·s in single-crystal transistors. The π stacking structure, which enhances π orbital overlap and facilitates carrier transport, may thus be responsible for this high mobility." @default.
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• W2022127834 date "2004-11-05" @default.
• W2022127834 modified "2023-10-16" @default.
• W2022127834 title "Synthesis, Crystal Structure, and Transistor Performance of Tetracene Derivatives" @default.
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• W2022127834 doi "https://doi.org/10.1021/ja045208p" @default.
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