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- W2022129638 abstract "We describe here a divergent total synthesis of all of the four stereoisomers of dihydrokawain-5-ol starting from α-d-glucose. The approach involves the use of Ando's modification of Horner−Wadsworth−Emmons homologation to give a α,β-unsaturated ester. Subsequently, lactonization and 1,4-addition of OMe group in one step provided a δ-lactone, which was converted into the target compounds in two steps." @default.
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- W2022129638 date "2004-04-20" @default.
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- W2022129638 title "Facile One-Step Synthesis of β-Alkoxy Lactone via Sequential Lactonization and 1,4-Addition of Alkoxide Group: Total Synthesis of All Stereoisomers of Dihydrokawain-5-ol" @default.
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- W2022129638 doi "https://doi.org/10.1021/jo049858n" @default.
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