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- W2022130564 abstract "The new method for preparing OsO3F2 is presented. Its crystal structure reveals a polymeric chain structure with distorted octahedral geometry for the OsO3F3 units and symmetrical, non-linear fluorine bridges. The OsO3F3 unit has a facial geometry. This structure is not in accord with predictions on the molecular structure of OsO3F2. OsO2F4, obtained from KrF2 and OsO4, crystallizes in the space group P61 forming a sixfold helical chain arrangement of nearly octahedral OsO2F4 molecules. Oxygen or fluorine atoms are partially disordered. The cis orientation of the two oxygen atoms is established by means of NMR, vibrational spectroscopy, and X-ray data." @default.
- W2022130564 created "2016-06-24" @default.
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- W2022130564 date "2010-08-20" @default.
- W2022130564 modified "2023-09-25" @default.
- W2022130564 title "ChemInform Abstract: OsO3F2 and OsO2F4, Preparation and Crystal Structures." @default.
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- W2022130564 doi "https://doi.org/10.1002/chin.199339047" @default.
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