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• W2022132561 startingPage "9277" @default.
• W2022132561 abstract "By preparing methyl bromide (CH3Br) in selected rotational levels of the CH3Br(X̃1A1; v1 = 1) state with infrared (IR) laser excitation prior to vacuum-ultraviolet (VUV) laser pulsed field ionization-photoelectron (PFI-PE) measurements, we have observed rotationally resolved photoionization transitions to the CH3Br+(X̃2E3/2; v1+ = 1) state, where v1 and v1+ are the symmetric C−H stretching vibrational mode for the neutral and cation, respectively. The VUV-PFI-PE origin band for CH3Br+(X̃2E3/2) has also been measured. The simulation of these IR-VUV-PFI-PE and VUV-PFI-PE spectra have allowed the determination of the v1+ vibrational frequency (2901.8 ± 0.5 cm−1) and the ionization energies of the origin band (85 028.3 ± 0.5 cm−1) and the v1+ = 1 ← v1 = 1 band (84 957.9 ± 0.5 cm−1)." @default.
• W2022132561 created "2016-06-24" @default.
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• W2022132561 date "2008-05-28" @default.
• W2022132561 modified "2023-09-23" @default.
• W2022132561 title "Infrared Vacuum-Ultraviolet Laser Pulsed Field Ionization-Photoelectron Study of CH₃Br⁺(<i>X̃</i>²E_3/2)" @default.
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• W2022132561 doi "https://doi.org/10.1021/jp8019649" @default.
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