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- W2022133051 abstract "The relative intensities of light by compounds of 46 elements have been measured following irradiation, by electrodeless discharge lamps, of the particles formed in H2-air and C2H2-air flames. A procedure which enables signals from the detector to be normalized allows comparison of results which vary greatly in absolute magnitude. Scattering by unseeded flames is shown to be significant when the flame is not in thermal equilibrium with the environment. In an H2-air flame, scattering resulting from the nebulization of 0.05 m solutions containing the following elements is found to decrease in the series Th > La > Al > Si > Ir > U > Pt > Rh ⋍ Ru > Ti > Zr ⋍ Ce ⋍ Ca > Os ⋍ Mn ⋍ Tl ⋍ Pd. Compounds of other elements investigated did not lead to significant scattered radiation. The scattering is dependent upon flame composition and temperature, the form of the element as nebulized and apparently the extent of cohesion between non-volatile particles. Light scattering by the Pt group metals is considered to occur as a result of interatomic bonding." @default.
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- W2022133051 date "1979-01-01" @default.
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- W2022133051 title "Particulate light scattering dependence upon solute compound in atomic flame spectrometry" @default.
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- W2022133051 doi "https://doi.org/10.1016/0584-8547(79)80007-5" @default.
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