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- W2022133719 abstract "The novel 1,6-amino addition reaction to the naphthalene ring system followed by the electrophilic alkylation is presented. The detailed mechanistic studies suggest the existence of two equilibrations that result in the 1,4-amino addition reaction and the 1,6-amino addition reaction. The stability and bulkiness of lithium amide play a key role in directing the course of the reaction. The transformation of the 1,6-amino adducts to other useful compounds is concisely demonstrated. The methodology provides a remote-controlled diastereoselective synthesis of δ-amino acid derivatives." @default.
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- W2022133719 date "1998-05-01" @default.
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- W2022133719 title "Diastereoselective conjugate 1,6-addition of lithium amides to naphthyloxazolines. Mechanistic studies and synthesis of δ-amino acid derivatives" @default.
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- W2022133719 doi "https://doi.org/10.1016/s0040-4020(98)00174-4" @default.
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