Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022138765> ?p ?o ?g. }
- W2022138765 endingPage "5158" @default.
- W2022138765 startingPage "5152" @default.
- W2022138765 abstract "Heating a toluene solution of bis(germyl)palladium complex [Pd(GeHPh2)2(dmpe)] (2) (dmpe = 1,2-bis(dimethylphosphino)ethane) at 70 °C produced a mixture of dipalladium complexes, one with bridging digermene and germylene ligands, [{Pd(dmpe)}2(μ-GePh2)(μ-Ge2Ph4)] (3), and also a mononuclear tetragermapalladacyclopentane, [Pd(GePh2GePh2GePh2GePh2)(dmpe)] (4), in 92:8 molar ratio, respectively. The reaction of H2GePh2 with 2 in 10:1 molar ratio formed complex 4 as the main product (3:4 = 4:96). Complexes 3 and 4 were isolated from the above reactions and characterized by X-ray crystallography and NMR spectroscopy. Complex 3 reacted with H2GePh2 (Pd:Ge = 1:10) at 80 °C to yield 4 quantitatively, whereas simple heating of 3 at the same temperature did not form 4 at all. Reaction pathways for the Ge−Ge bond formation are discussed." @default.
- W2022138765 created "2016-06-24" @default.
- W2022138765 creator A5013133169 @default.
- W2022138765 creator A5073662278 @default.
- W2022138765 creator A5074088191 @default.
- W2022138765 creator A5088181080 @default.
- W2022138765 date "2008-09-11" @default.
- W2022138765 modified "2023-10-18" @default.
- W2022138765 title "Mono- and Dinuclear Germapalladacycles Obtained via the Ge−Ge Bond Forming Reactions Promoted by Palladium Complexes" @default.
- W2022138765 cites W1186536418 @default.
- W2022138765 cites W1964390542 @default.
- W2022138765 cites W1967480115 @default.
- W2022138765 cites W1968508019 @default.
- W2022138765 cites W1969669311 @default.
- W2022138765 cites W1972962756 @default.
- W2022138765 cites W1978856191 @default.
- W2022138765 cites W1981517936 @default.
- W2022138765 cites W1981548068 @default.
- W2022138765 cites W1983920931 @default.
- W2022138765 cites W1986203214 @default.
- W2022138765 cites W1987474305 @default.
- W2022138765 cites W1990941507 @default.
- W2022138765 cites W1991173335 @default.
- W2022138765 cites W1991600639 @default.
- W2022138765 cites W1992459809 @default.
- W2022138765 cites W1993514736 @default.
- W2022138765 cites W1994039594 @default.
- W2022138765 cites W1995738352 @default.
- W2022138765 cites W1997318866 @default.
- W2022138765 cites W1999490229 @default.
- W2022138765 cites W2000306970 @default.
- W2022138765 cites W2002628083 @default.
- W2022138765 cites W2004783408 @default.
- W2022138765 cites W2006941595 @default.
- W2022138765 cites W2007479837 @default.
- W2022138765 cites W2007705497 @default.
- W2022138765 cites W2008637737 @default.
- W2022138765 cites W2008671488 @default.
- W2022138765 cites W2014610702 @default.
- W2022138765 cites W2018095142 @default.
- W2022138765 cites W2019648989 @default.
- W2022138765 cites W2021588167 @default.
- W2022138765 cites W2023345696 @default.
- W2022138765 cites W2027304262 @default.
- W2022138765 cites W2027466858 @default.
- W2022138765 cites W2031078585 @default.
- W2022138765 cites W2031319137 @default.
- W2022138765 cites W2031389586 @default.
- W2022138765 cites W2035098018 @default.
- W2022138765 cites W2035194528 @default.
- W2022138765 cites W2036091049 @default.
- W2022138765 cites W2037698731 @default.
- W2022138765 cites W2042197031 @default.
- W2022138765 cites W2044118785 @default.
- W2022138765 cites W2046061930 @default.
- W2022138765 cites W2052175455 @default.
- W2022138765 cites W2058342727 @default.
- W2022138765 cites W2058622985 @default.
- W2022138765 cites W2062523325 @default.
- W2022138765 cites W2066451698 @default.
- W2022138765 cites W2066466355 @default.
- W2022138765 cites W2067844139 @default.
- W2022138765 cites W2068462475 @default.
- W2022138765 cites W2069253371 @default.
- W2022138765 cites W2070393841 @default.
- W2022138765 cites W2072083983 @default.
- W2022138765 cites W2074850891 @default.
- W2022138765 cites W2075406738 @default.
- W2022138765 cites W2076778578 @default.
- W2022138765 cites W2077427482 @default.
- W2022138765 cites W2079366127 @default.
- W2022138765 cites W2086805072 @default.
- W2022138765 cites W2086907838 @default.
- W2022138765 cites W2086926904 @default.
- W2022138765 cites W2089923076 @default.
- W2022138765 cites W2109789796 @default.
- W2022138765 cites W2116950457 @default.
- W2022138765 cites W2123432535 @default.
- W2022138765 cites W2317274905 @default.
- W2022138765 cites W2325020192 @default.
- W2022138765 cites W289309775 @default.
- W2022138765 cites W2949084208 @default.
- W2022138765 cites W2949236922 @default.
- W2022138765 cites W2949359907 @default.
- W2022138765 cites W2949432792 @default.
- W2022138765 cites W2949517514 @default.
- W2022138765 cites W2949562834 @default.
- W2022138765 cites W2949737210 @default.
- W2022138765 cites W2949914338 @default.
- W2022138765 cites W2949963484 @default.
- W2022138765 cites W2950969265 @default.
- W2022138765 cites W2951184951 @default.
- W2022138765 cites W2951263662 @default.
- W2022138765 cites W2951989330 @default.
- W2022138765 cites W2953036415 @default.
- W2022138765 cites W3138293859 @default.
- W2022138765 cites W4211250996 @default.
- W2022138765 cites W4241721813 @default.