Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022141007> ?p ?o ?g. }
- W2022141007 endingPage "5164" @default.
- W2022141007 startingPage "5159" @default.
- W2022141007 abstract "Reaction of the terminal borylene complexes [(OC)5MBN(SiMe3)2] (M = Cr, W) with [M‘(PCy3)] (M‘ = Pd, Pt) at room temperature led to spontaneous formation of the heterodinuclear complexes [(OC)4M(μ-CO){μ-BN(SiMe3)2}M‘(PCy3)2] (M = Cr, M‘ = Pd; M = W, M‘ = Pd; M = Cr, M‘ = Pt) with concomitant liberation of PCy3. X-ray diffraction studies revealed that the borylene ligand adopts a semibridging position between the two different metal centers, thus establishing a new coordination mode for borylenes and providing further experimental evidence for the theoretically predicted close relationship between BR and CO. After prolonged reaction times the liberated phosphine substitutes the carbonyl group in trans-position to the borylene moiety, forming complexes of the type [(Cy3P)(OC)3M(μ-CO){μ-BN(SiMe3)2}M‘(PCy3)] (M = Cr, M‘ = Pt; M = W, M‘ = Pt; M = W, M‘ = Pd). Heating or photolytic activation of [(OC)4M(μ-CO){μ-BN(SiMe3)2}Pd(PCy3)] afforded the terminal borylene complexes trans-[(Cy3P)(OC)4MBN(SiMe3)2], which were fully characterized in the case of M = Cr. Structural data of trans-[(Cy3P)(OC)4CrBN(SiMe3)2] confirm the presence of an enhanced Cr−B π-back-donation imposed by the phosphine ligand in trans-position." @default.
- W2022141007 created "2016-06-24" @default.
- W2022141007 creator A5022474961 @default.
- W2022141007 creator A5028432392 @default.
- W2022141007 creator A5038029240 @default.
- W2022141007 creator A5056569207 @default.
- W2022141007 date "2006-09-08" @default.
- W2022141007 modified "2023-10-18" @default.
- W2022141007 title "Synthesis and Reactivity of Semibridging Borylene Complexes" @default.
- W2022141007 cites W1554733289 @default.
- W2022141007 cites W1972261223 @default.
- W2022141007 cites W1972588239 @default.
- W2022141007 cites W1975075419 @default.
- W2022141007 cites W1986538411 @default.
- W2022141007 cites W1994935625 @default.
- W2022141007 cites W2008135795 @default.
- W2022141007 cites W2008422287 @default.
- W2022141007 cites W2011046689 @default.
- W2022141007 cites W2027102899 @default.
- W2022141007 cites W2028233051 @default.
- W2022141007 cites W2040082220 @default.
- W2022141007 cites W2043445404 @default.
- W2022141007 cites W2049122706 @default.
- W2022141007 cites W2053275142 @default.
- W2022141007 cites W2058331313 @default.
- W2022141007 cites W2059231094 @default.
- W2022141007 cites W2061369629 @default.
- W2022141007 cites W2064997386 @default.
- W2022141007 cites W2066270136 @default.
- W2022141007 cites W2070915726 @default.
- W2022141007 cites W2083630140 @default.
- W2022141007 cites W2085054675 @default.
- W2022141007 cites W2087919641 @default.
- W2022141007 cites W2090646068 @default.
- W2022141007 cites W2092456326 @default.
- W2022141007 cites W2114896890 @default.
- W2022141007 cites W2114962900 @default.
- W2022141007 cites W2124249145 @default.
- W2022141007 cites W2127484138 @default.
- W2022141007 cites W2138079813 @default.
- W2022141007 cites W2144436899 @default.
- W2022141007 cites W2153368439 @default.
- W2022141007 cites W2322383385 @default.
- W2022141007 cites W2949846648 @default.
- W2022141007 cites W2951193720 @default.
- W2022141007 cites W2952355584 @default.
- W2022141007 cites W2953270166 @default.
- W2022141007 cites W4233994016 @default.
- W2022141007 cites W4245360495 @default.
- W2022141007 doi "https://doi.org/10.1021/om0605480" @default.
- W2022141007 hasPublicationYear "2006" @default.
- W2022141007 type Work @default.
- W2022141007 sameAs 2022141007 @default.
- W2022141007 citedByCount "61" @default.
- W2022141007 countsByYear W20221410072012 @default.
- W2022141007 countsByYear W20221410072013 @default.
- W2022141007 countsByYear W20221410072014 @default.
- W2022141007 countsByYear W20221410072015 @default.
- W2022141007 countsByYear W20221410072020 @default.
- W2022141007 countsByYear W20221410072021 @default.
- W2022141007 countsByYear W20221410072022 @default.
- W2022141007 crossrefType "journal-article" @default.
- W2022141007 hasAuthorship W2022141007A5022474961 @default.
- W2022141007 hasAuthorship W2022141007A5028432392 @default.
- W2022141007 hasAuthorship W2022141007A5038029240 @default.
- W2022141007 hasAuthorship W2022141007A5056569207 @default.
- W2022141007 hasConcept C116569031 @default.
- W2022141007 hasConcept C142724271 @default.
- W2022141007 hasConcept C155647269 @default.
- W2022141007 hasConcept C161790260 @default.
- W2022141007 hasConcept C170493617 @default.
- W2022141007 hasConcept C178790620 @default.
- W2022141007 hasConcept C185592680 @default.
- W2022141007 hasConcept C204787440 @default.
- W2022141007 hasConcept C2776568683 @default.
- W2022141007 hasConcept C2776910235 @default.
- W2022141007 hasConcept C2777716191 @default.
- W2022141007 hasConcept C544153396 @default.
- W2022141007 hasConcept C55493867 @default.
- W2022141007 hasConcept C71240020 @default.
- W2022141007 hasConcept C71924100 @default.
- W2022141007 hasConcept C8010536 @default.
- W2022141007 hasConceptScore W2022141007C116569031 @default.
- W2022141007 hasConceptScore W2022141007C142724271 @default.
- W2022141007 hasConceptScore W2022141007C155647269 @default.
- W2022141007 hasConceptScore W2022141007C161790260 @default.
- W2022141007 hasConceptScore W2022141007C170493617 @default.
- W2022141007 hasConceptScore W2022141007C178790620 @default.
- W2022141007 hasConceptScore W2022141007C185592680 @default.
- W2022141007 hasConceptScore W2022141007C204787440 @default.
- W2022141007 hasConceptScore W2022141007C2776568683 @default.
- W2022141007 hasConceptScore W2022141007C2776910235 @default.
- W2022141007 hasConceptScore W2022141007C2777716191 @default.
- W2022141007 hasConceptScore W2022141007C544153396 @default.
- W2022141007 hasConceptScore W2022141007C55493867 @default.
- W2022141007 hasConceptScore W2022141007C71240020 @default.
- W2022141007 hasConceptScore W2022141007C71924100 @default.
- W2022141007 hasConceptScore W2022141007C8010536 @default.