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- W2022141944 abstract "The metal-catalyzed synthesis of polyolefins, polyketones, and polycarbonates is well-known in academia and is already successfully applied in industrial processes. Still missing, however, is the metal-catalyzed synthesis of aliphatic polyesters, as one of the most important biodegradeable polymer families. We report here on the cobalt-catalyzed alternating copolymerization of propylene oxide and carbon monoxide, affording atactic and isotactic polyhydroxybutyrates (PHB). The postulated mechanism is supported by online ATR-IR analytics." @default.
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- W2022141944 date "2002-04-27" @default.
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- W2022141944 title "The Cobalt-Catalyzed Alternating Copolymerization of Epoxides and Carbon Monoxide: A Novel Approach to Polyesters" @default.
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- W2022141944 doi "https://doi.org/10.1021/ja0256919" @default.
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