Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022143598> ?p ?o ?g. }
Showing items 1 to 92 of
92
with 100 items per page.
- W2022143598 endingPage "20" @default.
- W2022143598 startingPage "15" @default.
- W2022143598 abstract "A series of mixed-valence compounds of general formula Ni(OAc)(LLLL)Ni(tdt)2, in which tdt stands for the toluene-3,4-dithiolate anion and LLLL is a tetradentate N2S2 donor with two (benz)imidazole groups and two thioether groups, has been prepared and characterized. The compounds are formed by spontaneous oxidation of the starting Ni(II) products in air. Characterization with spectroscopic measurements indicates cations Ni(LLLL)(OAc)+with divalent octahedral Ni(II), and anions Ni(tdt)2− with square planar Ni(III). The crystal structure of one of the compounds, i.e. with LLLL = 1,6-bis(benzimidazol-2-yl)-2,5-dithiahexanen (abbreviated bbdh), has been determined. The title compound crystallizes in space group P1, Z = 2, a = 14.132(7), b = 13.345(8), c = 10.906(7), α = 115.59(4), β = 91.58(5), γ = 100.74(4)°. The structure has been determined using conventional heavy atom methods, final Rw = 0.057 (including hydrogens) based on 3379 significant (I > 2σ(I)) reflections. Two anions Ni(tdt)2−, with Ni-S distances of 2.140(2)–2.153(2) Å, lie on centers of symmetry. There are strong indications of disorder in one of the Ni anions. The cation [Ni(OAc)(bbdh)]+ is six-coordinated by two oxygens of acetate (2.108(4) and 2.137(4) Å), two nitrogens of the benzimidazoles (2.026(5) and 2.047(5) Å), and two sulfurs of the thioethers (2.415(2) and 2.416(2) Å)." @default.
- W2022143598 created "2016-06-24" @default.
- W2022143598 creator A5012555611 @default.
- W2022143598 creator A5015264123 @default.
- W2022143598 creator A5017938590 @default.
- W2022143598 creator A5040905387 @default.
- W2022143598 creator A5052471303 @default.
- W2022143598 creator A5076678189 @default.
- W2022143598 date "1990-01-01" @default.
- W2022143598 modified "2023-09-25" @default.
- W2022143598 title "Synthesis, spectroscopy and magnetism of mixed-valence Ni(II)–Ni(III) compounds with (benz)imidazolethioether, acetates and dithiolates as ligands. Crystal structure of (acetato)(1,6-bis(benzimidazol-2-yl)-2,5-dithiahexane)nickel(II) bis(toluene-3,4-dithiolato)niccolate(III)" @default.
- W2022143598 cites W1968624572 @default.
- W2022143598 cites W1968903693 @default.
- W2022143598 cites W1969502414 @default.
- W2022143598 cites W1971992343 @default.
- W2022143598 cites W1976503704 @default.
- W2022143598 cites W1983519205 @default.
- W2022143598 cites W1988228282 @default.
- W2022143598 cites W2012563025 @default.
- W2022143598 cites W2013653091 @default.
- W2022143598 cites W2036302288 @default.
- W2022143598 cites W2038107317 @default.
- W2022143598 cites W2048322537 @default.
- W2022143598 cites W2059343227 @default.
- W2022143598 cites W2059461641 @default.
- W2022143598 cites W2062504163 @default.
- W2022143598 cites W2069431011 @default.
- W2022143598 cites W2079363489 @default.
- W2022143598 cites W2082640491 @default.
- W2022143598 cites W2090667652 @default.
- W2022143598 cites W2091601615 @default.
- W2022143598 cites W2329146555 @default.
- W2022143598 cites W2951303925 @default.
- W2022143598 cites W3004979009 @default.
- W2022143598 cites W3142810987 @default.
- W2022143598 cites W4238921219 @default.
- W2022143598 doi "https://doi.org/10.1016/s0020-1693(00)83932-8" @default.
- W2022143598 hasPublicationYear "1990" @default.
- W2022143598 type Work @default.
- W2022143598 sameAs 2022143598 @default.
- W2022143598 citedByCount "12" @default.
- W2022143598 countsByYear W20221435982012 @default.
- W2022143598 countsByYear W20221435982017 @default.
- W2022143598 countsByYear W20221435982018 @default.
- W2022143598 crossrefType "journal-article" @default.
- W2022143598 hasAuthorship W2022143598A5012555611 @default.
- W2022143598 hasAuthorship W2022143598A5015264123 @default.
- W2022143598 hasAuthorship W2022143598A5017938590 @default.
- W2022143598 hasAuthorship W2022143598A5040905387 @default.
- W2022143598 hasAuthorship W2022143598A5052471303 @default.
- W2022143598 hasAuthorship W2022143598A5076678189 @default.
- W2022143598 hasConcept C115624301 @default.
- W2022143598 hasConcept C155647269 @default.
- W2022143598 hasConcept C168900304 @default.
- W2022143598 hasConcept C178790620 @default.
- W2022143598 hasConcept C185592680 @default.
- W2022143598 hasConcept C198819137 @default.
- W2022143598 hasConcept C2779444094 @default.
- W2022143598 hasConcept C2780874372 @default.
- W2022143598 hasConcept C71240020 @default.
- W2022143598 hasConcept C8010536 @default.
- W2022143598 hasConceptScore W2022143598C115624301 @default.
- W2022143598 hasConceptScore W2022143598C155647269 @default.
- W2022143598 hasConceptScore W2022143598C168900304 @default.
- W2022143598 hasConceptScore W2022143598C178790620 @default.
- W2022143598 hasConceptScore W2022143598C185592680 @default.
- W2022143598 hasConceptScore W2022143598C198819137 @default.
- W2022143598 hasConceptScore W2022143598C2779444094 @default.
- W2022143598 hasConceptScore W2022143598C2780874372 @default.
- W2022143598 hasConceptScore W2022143598C71240020 @default.
- W2022143598 hasConceptScore W2022143598C8010536 @default.
- W2022143598 hasIssue "1" @default.
- W2022143598 hasLocation W20221435981 @default.
- W2022143598 hasOpenAccess W2022143598 @default.
- W2022143598 hasPrimaryLocation W20221435981 @default.
- W2022143598 hasRelatedWork W167857991 @default.
- W2022143598 hasRelatedWork W1969215021 @default.
- W2022143598 hasRelatedWork W1969352129 @default.
- W2022143598 hasRelatedWork W2039836026 @default.
- W2022143598 hasRelatedWork W2041243255 @default.
- W2022143598 hasRelatedWork W2065836250 @default.
- W2022143598 hasRelatedWork W2066835553 @default.
- W2022143598 hasRelatedWork W2074779033 @default.
- W2022143598 hasRelatedWork W2324887520 @default.
- W2022143598 hasRelatedWork W2950083354 @default.
- W2022143598 hasVolume "167" @default.
- W2022143598 isParatext "false" @default.
- W2022143598 isRetracted "false" @default.
- W2022143598 magId "2022143598" @default.
- W2022143598 workType "article" @default.