Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022146536> ?p ?o ?g. }
- W2022146536 endingPage "1764" @default.
- W2022146536 startingPage "1759" @default.
- W2022146536 abstract "Synthesis of perfluoroalkylated (E)-allylic alcohols by the ‘one-pot’ reaction of equimolar amounts of aldehyde, 3-bromo-1,1,1-trifluoroacetone (or α-bromoalkyl perfluoroalkyl ketone), triphenylphosphine and titanium(IV) isopropoxide is described. The reductive olefination products were obtained in good yields exclusively in E-form. Thus this methodology provides a very convenient synthesis of perfluoroalkylated (E)-allylic alcohols and the widespread use of these allylic alcohols is quite important in organic synthesis. They are interesting fluorinated building blocks, not easily available by existing synthetic methods. A possible mechanism for the explanation of formation of reductive olefinic products and the stereochemical results is proposed." @default.
- W2022146536 created "2016-06-24" @default.
- W2022146536 creator A5019103134 @default.
- W2022146536 creator A5025735445 @default.
- W2022146536 creator A5064840674 @default.
- W2022146536 date "1999-01-01" @default.
- W2022146536 modified "2023-10-18" @default.
- W2022146536 title "One-pot stereoselective synthesis of perfluoroalkylated (E )-allylic alcohols mediated by Ti(OPri)4 and Ph3P 1" @default.
- W2022146536 cites W1971015732 @default.
- W2022146536 cites W1989055412 @default.
- W2022146536 cites W1991434976 @default.
- W2022146536 cites W1992183428 @default.
- W2022146536 cites W1997084982 @default.
- W2022146536 cites W2000141610 @default.
- W2022146536 cites W2001814389 @default.
- W2022146536 cites W2003426759 @default.
- W2022146536 cites W2006941341 @default.
- W2022146536 cites W2012119357 @default.
- W2022146536 cites W2014349079 @default.
- W2022146536 cites W2016881940 @default.
- W2022146536 cites W2019653148 @default.
- W2022146536 cites W2024720193 @default.
- W2022146536 cites W2027534627 @default.
- W2022146536 cites W2029771239 @default.
- W2022146536 cites W2030291376 @default.
- W2022146536 cites W2036549666 @default.
- W2022146536 cites W2036673845 @default.
- W2022146536 cites W2039378923 @default.
- W2022146536 cites W2059343990 @default.
- W2022146536 cites W2060105902 @default.
- W2022146536 cites W2066517913 @default.
- W2022146536 cites W2074206375 @default.
- W2022146536 cites W2077372897 @default.
- W2022146536 cites W2089701789 @default.
- W2022146536 cites W2094951660 @default.
- W2022146536 cites W2097747776 @default.
- W2022146536 cites W2114675513 @default.
- W2022146536 cites W2114996492 @default.
- W2022146536 cites W2121641845 @default.
- W2022146536 cites W2125279549 @default.
- W2022146536 cites W2125924908 @default.
- W2022146536 cites W2126254583 @default.
- W2022146536 cites W2131772380 @default.
- W2022146536 cites W2142509594 @default.
- W2022146536 cites W2142848650 @default.
- W2022146536 cites W2154585462 @default.
- W2022146536 cites W2167938724 @default.
- W2022146536 cites W2172121313 @default.
- W2022146536 cites W2325924562 @default.
- W2022146536 cites W2949146977 @default.
- W2022146536 cites W2949796300 @default.
- W2022146536 cites W2949822751 @default.
- W2022146536 cites W2950060685 @default.
- W2022146536 cites W2950593017 @default.
- W2022146536 cites W2951318169 @default.
- W2022146536 cites W2951910762 @default.
- W2022146536 cites W2953092632 @default.
- W2022146536 cites W1968124833 @default.
- W2022146536 doi "https://doi.org/10.1039/a809127g" @default.
- W2022146536 hasPublicationYear "1999" @default.
- W2022146536 type Work @default.
- W2022146536 sameAs 2022146536 @default.
- W2022146536 citedByCount "3" @default.
- W2022146536 countsByYear W20221465362015 @default.
- W2022146536 crossrefType "journal-article" @default.
- W2022146536 hasAuthorship W2022146536A5019103134 @default.
- W2022146536 hasAuthorship W2022146536A5025735445 @default.
- W2022146536 hasAuthorship W2022146536A5064840674 @default.
- W2022146536 hasConcept C120095180 @default.
- W2022146536 hasConcept C161790260 @default.
- W2022146536 hasConcept C178790620 @default.
- W2022146536 hasConcept C181647583 @default.
- W2022146536 hasConcept C185592680 @default.
- W2022146536 hasConcept C2777247709 @default.
- W2022146536 hasConcept C2777738585 @default.
- W2022146536 hasConcept C2779825165 @default.
- W2022146536 hasConcept C2909674642 @default.
- W2022146536 hasConceptScore W2022146536C120095180 @default.
- W2022146536 hasConceptScore W2022146536C161790260 @default.
- W2022146536 hasConceptScore W2022146536C178790620 @default.
- W2022146536 hasConceptScore W2022146536C181647583 @default.
- W2022146536 hasConceptScore W2022146536C185592680 @default.
- W2022146536 hasConceptScore W2022146536C2777247709 @default.
- W2022146536 hasConceptScore W2022146536C2777738585 @default.
- W2022146536 hasConceptScore W2022146536C2779825165 @default.
- W2022146536 hasConceptScore W2022146536C2909674642 @default.
- W2022146536 hasIssue "12" @default.
- W2022146536 hasLocation W20221465361 @default.
- W2022146536 hasOpenAccess W2022146536 @default.
- W2022146536 hasPrimaryLocation W20221465361 @default.
- W2022146536 hasRelatedWork W1985589377 @default.
- W2022146536 hasRelatedWork W1992899476 @default.
- W2022146536 hasRelatedWork W1993597733 @default.
- W2022146536 hasRelatedWork W2014410305 @default.
- W2022146536 hasRelatedWork W2064865360 @default.
- W2022146536 hasRelatedWork W2079972202 @default.
- W2022146536 hasRelatedWork W2080646098 @default.
- W2022146536 hasRelatedWork W2095873828 @default.