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- W2022146970 abstract "Abstract The depth profiles of films formed on a commercial 18%-Cr ferritic stainless steel (SS) in the passive and transpassive zones were investigated using x-ray photoelectron spectroscopy (XPS) and angle-resolved XPS. Depth profiles (by sputtering) was performed by a 2 Kev Ar+ ion gun. The following two main differences between the passive and the transpassive layers were revealed: (1) The integral M-OH (hydroxide) to M-O (metal-oxygen) bond concentration ratio is a lot higher for the passive than for the transpassive zone.(2) The distribution profiles of M-O and M-OH bonds is approximately homogeneous over the depth of the transpassive film (except for a slight OH enrichment of the uppermost layer). The passive layer, on the other hand, exhibits a gradient of M-OH bond concentration with a maximum at the uppermost layer. It is suggested that M-OH profiles can be used to predict repassivation kinetics of SS alloys." @default.
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- W2022146970 date "1988-07-01" @default.
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- W2022146970 title "Studies of Metal-Oxygen Bonds on 18%-Cr Stainless Steel in the Passive and Transpassive Regions by Integrated and Angle-Resolved X-Ray Photoelectron Spectroscopies" @default.
- W2022146970 doi "https://doi.org/10.5006/1.3583962" @default.
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