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- W2022147436 abstract "The crystal structure of parasibirskite (CaHBO3) obtained at Fuka, Okayama Prefecture, Japan, was determined by Monte Carlo simulation using powder X-ray diffraction data and confirmed by Rietveld refinement. Parasibirskite is monoclinic with space group P21/m and cell constants a = 6.722(4), b = 5.437(2), c = 3.555(2) A, and β = 93.00(5)°. The calcium atom is surrounded by seven oxygen atoms with a monocapped distorted trigonal prism arrangement. The edge-shared CaO7 polyhedra form a layer structure elongated along the crystallographic b- and c-axes. These CaO7 layers are connected to each other by BO3 triangles, thus forming the parasibirskite structure. The hydrogen atom was presumed to connect to the O1 atom from the bond-valence calculation. Parasibirskite is a dimorph of sibirskite (CaHBO3), which consists of CaO6 double chains connected by BO3 triangles." @default.
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- W2022147436 date "2010-01-01" @default.
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- W2022147436 title "Crystal structure of parasibirskite (CaHBO3) and polymorphism in sibirskite and parasibirskite" @default.
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- W2022147436 doi "https://doi.org/10.2465/jmps.091015b" @default.
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