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• W2022152619 endingPage "4068" @default.
• W2022152619 startingPage "4056" @default.
• W2022152619 abstract "A highly enantioselective desymmetrization of meso cyclopent-2-ene-1,4-diethyl dicarbonates has been developed using a Rh-catalyzed asymmetric allylic substitution. Depending on the type of ligand used, each of two regioisomeric products can be obtained in good yield and excellent enantioselectivity. Under rhodium(I) catalysis, bisphosphine P-Phos ligands form trans-1,2-arylcyclopentenols as the major product, whereas Segphos ligands lead predominantly to trans-1,4-arylcyclopentenols." @default.
• W2022152619 created "2016-06-24" @default.
• W2022152619 creator A5034830599 @default.
• W2022152619 creator A5041929760 @default.
• W2022152619 creator A5044555614 @default.
• W2022152619 creator A5051090246 @default.
• W2022152619 creator A5067819769 @default.
• W2022152619 date "2010-05-14" @default.
• W2022152619 modified "2023-10-17" @default.
• W2022152619 title "Ligand-Controlled Selectivity in the Desymmetrization of <i>meso</i> Cyclopenten-1,4-diols via Rhodium(I)-Catalyzed Addition of Arylboronic Acids" @default.
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• W2022152619 doi "https://doi.org/10.1021/jo100391e" @default.
• W2022152619 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20469847" @default.
• W2022152619 hasPublicationYear "2010" @default.
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