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• W2022155468 abstract "The surface self-diffusion coefficient, Ds, for silver in atmospheres of hydrogen and hydrogen sulphide has been measured from the growth rate of grain boundary grooves. The results cover the temperature range 600°C to 900°C and values of the ratio of the partial pressures, p>H2SpH2, from 0 to 0.20. The presence of adsorbed sulphur increases Ds by factors as high as about 104. Adsorption isotherms show that Ds continues to increase with pH2SpH2, even after the surface has been effectively saturated by a monolayer of adsorbed sulphur. A diffusion mechanism is proposed, whereby a metal atom jumping to a site occupied by an adsorbed sulphur atom is scattered and continues in “semi-free translation”, until it finds an empty site in the adsorbed layer. The results are interpreted in terms of this model." @default.
• W2022155468 created "2016-06-24" @default.
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• W2022155468 date "1967-06-01" @default.
• W2022155468 modified "2023-10-01" @default.
• W2022155468 title "The effect of adsorbed sulphur on the surface self-diffusion of silver" @default.
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• W2022155468 doi "https://doi.org/10.1016/0039-6028(67)90124-0" @default.
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