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- W2022155785 abstract "The compound Bi 7 − δ Ni 2 Br 5 − 2δ = (Bi 3 Ni) 2 [Bi 1 − δ Br 4 ]Br 1 −2δ (δ = 1/9) is a sub-bromide of the intermetallic phase Bi 3 Ni. Its crystal structure contains metallic rods, ^1_{infty}[Bi 3 Ni], which are embedded in a salt-like matrix of bromido-bismuthate(III) and bromide anions. The non-stoichiometry originates from the variation of the number n of trans edge-sharing octahedra in the [Bi n Br 4 n + 2 ] ( n + 2)− oligomers (3 ≤ n ≤ 5), as well as from vacancies on the sites of the isolated Br atoms. The simplified structure is described in the orthorhombic space group Cmcm with a = 4.0660 (4), b = 23.305 (3), c = 17.130 (2) Å. It shows a statistical distribution of vacancies and orientational disorder of the concatenated octahedra. By choosing the modulation vector q = a */9 + b */2, the additional weak reflections of the diffraction pattern can be indexed. In the [3 + 1]-dimensional superspace group Pmnm (α½0)000, an ordered structure model is achieved. The modulated crystal structure bears a strong resemblance to the somewhat higher oxidized sub-bromide Bi 7 − δ Ni 2 Br 5 (δ = 1/9)." @default.
- W2022155785 created "2016-06-24" @default.
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- W2022155785 date "2009-09-17" @default.
- W2022155785 modified "2023-10-18" @default.
- W2022155785 title "Superspace description of the modulated structure of the metal-salt-hybrid Bi<sub>7 − δ</sub>Ni<sub>2</sub>Br<sub>5 − 2δ</sub> (δ = 1/9)" @default.
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- W2022155785 doi "https://doi.org/10.1107/s0108768109029760" @default.
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