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- W2022155928 abstract "Chlorinated paraffin and its derivative, dehydrohalogenated paraffin were studied by laser-Raman spectroscopy. It is shown that the dehydrohalogenation reaction leads to almost complete elimination of chlorine from the chain backbone with formation of polyyne segments of 3 to 10 acetylenic units as can be deduced from the triple bond stretching band at 2170 cm−1 for the sample having shorter polyyne segments and 2095 cm−1 for the sample with longer polyyne segments. The presence of polyene segments is underlined by the intense band at 1500 cm−1 in both samples studied. The thermogravimetric analysis of dehydrohalogenated paraffin as well as the differential thermal analysis has been performed in comparison to carbyne and graphite samples used as references." @default.
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- W2022155928 date "2000-07-17" @default.
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- W2022155928 title "RAMAN SPECTRA AND THERMAL ANALYSIS ON POLYYNE AND POLYENE-YNE CHAIN SEGMENTS" @default.
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- W2022155928 doi "https://doi.org/10.1081/ma-100101129" @default.
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