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• W2022157158 abstract "Using a time of flight (TOF) mass spectrometer, we obtained the multiphoton ionization (MPI) spectra of ethylamine (EA) and dimethylamine (DMA) molecules in the region of 440 nm–470 nm with a dye laser and at 532 nm with a Nd:YAG laser respectively. Both kinds of molecular ions are formed through resonance enhanced multiphoton ionization (REMPI) via Rydberg states. The fragment ions come from the dissociation of the corresponding molecular ion. The MPI-MS patterns of the two isomers are readily distinguished. The β-cleavage of the EA molecular ion is dominant. The currents of the molecular ion and the ion created by its pseudo-β cleavage are strongest in the MPI-MS of the DMA molecule. Softer ionization occurs at longer wavelengths as the initially formed molecular ions have less excess energy. The reactions of CH4N+ ions from different precursors are also structure related: they fragment more extensively in MPI of DMA molecules than in that of EA molecules." @default.
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• W2022157158 date "1998-11-01" @default.
• W2022157158 modified "2023-10-16" @default.
• W2022157158 title "REMPI time-of-flight mass spectra of C2H7N isomers" @default.
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• W2022157158 doi "https://doi.org/10.1016/s0030-4018(98)00457-x" @default.
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