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• W2022159072 abstract "Abstract Friedel–Crafts acylation of ruthenocene with (η5-chloroformylcyclopentadienyl)dicarbonylnitrosylchromium 15 has afforded cynichrodenyl ruthenocenyl ketone 6 in 39% yield. Reduction of 6 and acetylcynichrodene 11 with lithium aluminum hydride/aluminum chloride leads to cynichrodenylruthenocenylmethane 8 and ethylcynichrodene 2 in 45% and 63% yield, respectively. Structures of compound 6 and 8 have been solved by X-ray diffraction studies. Both cisoid and transoid conformations at the organic carbonyl carbon were observed in 6. The twist angle is 177.2°, 105.8°, 72.3°, and 24.4° for NO ligand of Cp(CO)2(NO) moiety in 5, transoid 6, cisoid 6, and 8, respectively. Compared the HetCOR NMR data of 6–8 with those of their ferrocene analogues, the opposite correlation was observed on the chemical shift assignments of C(2)–C(5) of Cp(Cr) in compound 5 and 6, while the correlation in compound 7 and 8 is the same. The electron density distribution in the cyclopentadienyl ring is discussed on the basis of 13C NMR data and those of 5, 8, and 9 are compared with the calculations via density functional B3LYP correlation-exchange method." @default.
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• W2022159072 date "2009-01-01" @default.
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• W2022159072 title "Unequivocal assignments of C(2,5) and C(3,4) on the Cp ring of scynichrodene derivatives bearing an electron-donating substituent in 13C NMR spectra and X-ray structures of (CO)2(NO)Cr[(η5-C5H4)-C(O)-(η5-C5H4)]Ru(η5-C5H5) and (CO)2(NO)Cr[(η5-C5H4)–CH2–(η5-C5H4)]Ru(η5-C5H5)" @default.
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• W2022159072 doi "https://doi.org/10.1016/j.jorganchem.2008.10.041" @default.
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