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• W2022160738 abstract "Lithium-7 NMR spectrometry was used to study the complexation reaction between lithium ions and several 12-, 15- and 18-membered crown ethers in a number of binary acetonitrile-nitrobenzene mixtures. Formation constants of the resulting 1:1 complexes in different solvent mixtures were determined by computer fitting of the chemical shift-mole ratio data. There is an inverse relationship between the complex stability and the amount of acetonitrile in the mixed solvent. Among different sized crown ethers used, 15-crowns were found to form the most stable Li+ complexes in the series. The influence of substitution on the macrocyclic rings on the stability of the resulting complexes is discussed." @default.
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• W2022160738 date "2001-08-01" @default.
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• W2022160738 title "Nuclear Magnetic Resonance Study of the Stoichiometry and Stability of Several Li+-Crown Ether Complexes in Various Acetonitrile-Nitrobenzene Mixtures" @default.
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• W2022160738 doi "https://doi.org/10.1002/jccs.200100104" @default.
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