FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022160940> ?p ?o ?g. }

• W2022160940 endingPage "695" @default.
• W2022160940 startingPage "689" @default.
• W2022160940 abstract "This study utilizes photoelectron spectroscopy (PES) combined with theoretical methods to determine the electronic structure contributions to the large reduction potential difference between [FeCl4]2-,1- and [Fe(SR)4]2-,1- (ΔE0 ≈ 1 V). Valence PES data confirm that this effect results from electronic structure differences because there is a similarly large shift in the onset of valence ionization between the two reduced species (ΔIvert = 1.4 ± 0.3 eV). Specific electronic contributions to ΔIvert have been investigated and defined. Ligand field effects, which are often considered to be of great importance, contribute very little to ΔIvert (ΔELF < −0.05 eV). By contrast, electronic relaxation, a factor that is often neglected in the analysis of chemical reactivity, strongly affects the valence ionization energies of both species. The larger electronic relaxation in the tetrathiolate allows it to more effectively stabilize the oxidized state and lowers its Ivert relative to that of the chloride (ΔErlx = 0.2 eV). The largest contribution to the difference in redox potentials is the much lower effective charge ( ) of the tetrathiolate in the reduced state, which results in a large difference in the energy of the Fe 3d manifold between the two redox couples (ΔEFe 3d = 1.2 eV). This difference derives from the significantly higher covalency of the iron−thiolate bond, which decreases and significantly lowers its redox potential." @default.
• W2022160940 created "2016-06-24" @default.
• W2022160940 creator A5024342453 @default.
• W2022160940 creator A5070204678 @default.
• W2022160940 date "2003-01-16" @default.
• W2022160940 modified "2023-10-12" @default.
• W2022160940 title "Electronic Structure Contributions to Electron-Transfer Reactivity in Iron−Sulfur Active Sites: 2. Reduction Potentials" @default.
• W2022160940 cites W1618038277 @default.
• W2022160940 cites W1980723764 @default.
• W2022160940 cites W1980919883 @default.
• W2022160940 cites W1993774897 @default.
• W2022160940 cites W1996108448 @default.
• W2022160940 cites W2003680693 @default.
• W2022160940 cites W2003962650 @default.
• W2022160940 cites W2020114693 @default.
• W2022160940 cites W2028449279 @default.
• W2022160940 cites W2030687437 @default.
• W2022160940 cites W2038533471 @default.
• W2022160940 cites W2051681126 @default.
• W2022160940 cites W2071374824 @default.
• W2022160940 cites W2080977834 @default.
• W2022160940 cites W2085909236 @default.
• W2022160940 cites W2086957099 @default.
• W2022160940 cites W2150345533 @default.
• W2022160940 doi "https://doi.org/10.1021/ic0203318" @default.
• W2022160940 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12562182" @default.
• W2022160940 hasPublicationYear "2003" @default.
• W2022160940 type Work @default.
• W2022160940 sameAs 2022160940 @default.
• W2022160940 citedByCount "32" @default.
• W2022160940 countsByYear W20221609402012 @default.
• W2022160940 countsByYear W20221609402014 @default.
• W2022160940 countsByYear W20221609402017 @default.
• W2022160940 countsByYear W20221609402018 @default.
• W2022160940 countsByYear W20221609402019 @default.
• W2022160940 countsByYear W20221609402021 @default.
• W2022160940 countsByYear W20221609402022 @default.
• W2022160940 crossrefType "journal-article" @default.
• W2022160940 hasAuthorship W2022160940A5024342453 @default.
• W2022160940 hasAuthorship W2022160940A5070204678 @default.
• W2022160940 hasConcept C121332964 @default.
• W2022160940 hasConcept C123669783 @default.
• W2022160940 hasConcept C142724271 @default.
• W2022160940 hasConcept C145148216 @default.
• W2022160940 hasConcept C147192597 @default.
• W2022160940 hasConcept C147597530 @default.
• W2022160940 hasConcept C147789679 @default.
• W2022160940 hasConcept C168900304 @default.
• W2022160940 hasConcept C175708663 @default.
• W2022160940 hasConcept C178790620 @default.
• W2022160940 hasConcept C179104552 @default.
• W2022160940 hasConcept C185592680 @default.
• W2022160940 hasConcept C198291218 @default.
• W2022160940 hasConcept C204787440 @default.
• W2022160940 hasConcept C2776910235 @default.
• W2022160940 hasConcept C2778591166 @default.
• W2022160940 hasConcept C46141821 @default.
• W2022160940 hasConcept C51286037 @default.
• W2022160940 hasConcept C544153396 @default.
• W2022160940 hasConcept C55904794 @default.
• W2022160940 hasConcept C71924100 @default.
• W2022160940 hasConcept C86025842 @default.
• W2022160940 hasConceptScore W2022160940C121332964 @default.
• W2022160940 hasConceptScore W2022160940C123669783 @default.
• W2022160940 hasConceptScore W2022160940C142724271 @default.
• W2022160940 hasConceptScore W2022160940C145148216 @default.
• W2022160940 hasConceptScore W2022160940C147192597 @default.
• W2022160940 hasConceptScore W2022160940C147597530 @default.
• W2022160940 hasConceptScore W2022160940C147789679 @default.
• W2022160940 hasConceptScore W2022160940C168900304 @default.
• W2022160940 hasConceptScore W2022160940C175708663 @default.
• W2022160940 hasConceptScore W2022160940C178790620 @default.
• W2022160940 hasConceptScore W2022160940C179104552 @default.
• W2022160940 hasConceptScore W2022160940C185592680 @default.
• W2022160940 hasConceptScore W2022160940C198291218 @default.
• W2022160940 hasConceptScore W2022160940C204787440 @default.
• W2022160940 hasConceptScore W2022160940C2776910235 @default.
• W2022160940 hasConceptScore W2022160940C2778591166 @default.
• W2022160940 hasConceptScore W2022160940C46141821 @default.
• W2022160940 hasConceptScore W2022160940C51286037 @default.
• W2022160940 hasConceptScore W2022160940C544153396 @default.
• W2022160940 hasConceptScore W2022160940C55904794 @default.
• W2022160940 hasConceptScore W2022160940C71924100 @default.
• W2022160940 hasConceptScore W2022160940C86025842 @default.
• W2022160940 hasIssue "3" @default.
• W2022160940 hasLocation W20221609401 @default.
• W2022160940 hasLocation W20221609402 @default.
• W2022160940 hasOpenAccess W2022160940 @default.
• W2022160940 hasPrimaryLocation W20221609401 @default.
• W2022160940 hasRelatedWork W125800058 @default.
• W2022160940 hasRelatedWork W1965606104 @default.
• W2022160940 hasRelatedWork W2024909237 @default.
• W2022160940 hasRelatedWork W2058735300 @default.
• W2022160940 hasRelatedWork W2071556103 @default.
• W2022160940 hasRelatedWork W2319069891 @default.
• W2022160940 hasRelatedWork W3008958811 @default.
• W2022160940 hasRelatedWork W4210760586 @default.
• W2022160940 hasRelatedWork W4255596690 @default.

• next