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- W2022161464 startingPage "2923" @default.
- W2022161464 abstract "The melt polymerization of diglycerol with bicyclic anhydride monomers derived from a naturally occurring monoterpene provides an avenue for polyesters with a high degree of sustainability. The hydrophobic anhydrides are synthesized at ambient temperature via a solvent-free Diels–Alder reaction of α-phellandrene with maleic anhydride. Subsequent melt polymerizations with tetra-functional diglycerol are effective under a range of [diglycerol]/[anhydride] ratios. The hydrophobicity of α-phellandrene directly impacts the swelling behavior of the resulting polyesters. The low E factors (<2), large amount of bio-based content (>75 %), ambient temperature monomer synthesis, and polymer degradability represent key factors in the design of these sustainable polyesters." @default.
- W2022161464 created "2016-06-24" @default.
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- W2022161464 date "2014-08-19" @default.
- W2022161464 modified "2023-09-24" @default.
- W2022161464 title "Diglycerol-Based Polyesters: Melt Polymerization with Hydrophobic Anhydrides" @default.
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- W2022161464 doi "https://doi.org/10.1002/cssc.201402249" @default.
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