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- W2022161539 abstract "Iodine interacts with R2P(X)·[CH2]n·(X)PR2[R = Ph, X = S, n= 1 (L′); R = Ph, X = S, n= 2 (L2); or R = Me, X = S, n= O (L4)] to give charge-transfer adducts of the type L·2l2 or L·l2, whereas corresponding reactions with R2N·CS·S2·CS·NR2[R = Me (L5) or Et (L6)] give products of the type L′·l6 in which L′ is oxidised probablyto give a dication with the cyclised structure [graphic omitted]2+(A)(L8, R = Et; L9, R = Me) with two [l3]– as counter ions. The interactions of L′ with FeCl3, CO[BF4]2· 6H2O and CoCl2·6H2O (all in excess) in diethyl ether or acetone–chloroform also give products containing the species (A) in the following complexes; [L9][FeCl4]2, [L8][FeCl4]2, [L9][BF4]2 and [L9][CoCl4] as well as dithiocarbamato-complexes. Dimethylcarbamoyi dimethylthio-carbamoyl disulphide and bis(diethyldithiocarbamylthio)methane with FeCl3 are each thought to produce cyclised dications similar to (A). With the appropriate copper(II) salts (in excess) and L′ in acetone, the copper(III) derivatives [CuCl2(S2CNR2)] and [Cu(S2CNR2)2][BF4](R = Me or Et) have been isolated. In the first two cases when the solvent is changed to chloroform–ethanol the copper(II) derivatives [CuCl(S2CNR2)] are found. With Ni[BF4]2·6H2O and NiCl2·6H2O in excess and acetone as solvent, L′ gives [Ni(S2CNMe2)3]X (X = BF4– or Cl–), the oxidation state of nickel probably being IV, while excess of Fe[ClO4]2·6H2O gives the known iron(IV) derivative [Fe(S2CNMe2)3][ClO4]." @default.
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- W2022161539 date "1977-01-01" @default.
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- W2022161539 title "Sulphur-ligand–metal complexes. Part 7. The interaction of some diphosphine dichalcogenides and tetra-alkylthiuram disulphides with halogens and some first-row transition-metal salts" @default.
- W2022161539 doi "https://doi.org/10.1039/dt9770000565" @default.
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