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- W2022164706 abstract "The microwave-optical double-resonance spectrum of the cyanide radical molecule is interpreted. The complete fine, hyperfine energy matrix is set up using the (bβJ) and (aβ) coupling cases as bases and the energies are obtained by diagonalizing the energy matrix. The fine and hyperfine interaction parameters are found by an iterative procedure which gives the set of parameters which best fits the observed spectrum. For the cyanide radical the results obtained are δ(B2Σ+J = 7/2→ J = 9/2fine-structure separation) = 500 ± 10MHz, ϱ2 (mixing parameter forJ = 7/2) = 0.152 ± 0.01, bΣ = 470 ± 10MHz, cΣ = 55 ± 10MHz, eQqΣ = −5 ± 5MHz, (aπ + 0.775 bπ + 0.496 cπ) = 60 ± 10MHz, eQqπ = 1.5 ± 5MHz, eQq2 < 10MHz for the A2II (v = 10) and B2Σ+ (v = 0) vibronic states." @default.
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- W2022164706 date "1972-11-01" @default.
- W2022164706 modified "2023-09-27" @default.
- W2022164706 title "The analysis of the hyperfine structure of the A2II(v = 10) and B2Σ+(v = 0) states of the CN radical molecule" @default.
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- W2022164706 doi "https://doi.org/10.1016/0022-2852(72)90101-4" @default.
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