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• W2022164914 abstract "[reaction: see text] The redox potentials of a highly constrained [2]rotaxane have been measured and used to model the energy of the HOMO of tetrathiafulvalene-based bistable [2]rotaxanes in their two co-conformationally isomeric states. Restrained from co-conformational movements, the measured oxidation and reduction potentials provide insights into the orbital energies and electronic structure of a (monopyrrolo)tetrathiafulvalene unit when encircled by a tetracationic cyclobis(paraquat-p-phenylene) ring." @default.
• W2022164914 created "2016-06-24" @default.
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• W2022164914 date "2006-05-01" @default.
• W2022164914 modified "2023-10-05" @default.
• W2022164914 title "Locking down the Electronic Structure of (Monopyrrolo)tetrathiafulvalene in [2]Rotaxanes" @default.
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• W2022164914 doi "https://doi.org/10.1021/ol060319+" @default.
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