Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022166903> ?p ?o ?g. }
Showing items 1 to 62 of
62
with 100 items per page.
- W2022166903 endingPage "1551" @default.
- W2022166903 startingPage "1551" @default.
- W2022166903 abstract "The photoelectron spectra of boron trifluoride, trichloride, tribromide, and tri-iodide have been obtained by use of a cylindrical deflection analyser instrument and HeI resonance radiation. Vertical ionization potentials, and in most cases adiabatic ionization potential also, are tabulated. Vibrational fine structure is observed in the BF3 and BCl3 spectra, and some of the bands of BBr3 and Bl3 show splittings ascribed to spin–orbit coupling. The spectra are interpreted on the basis of band splittings, fine structure, and correlation with the results of calculations; the BF3 assignment is in good agreement with recent Gaussian basis molecular orbital calculations. From the energies of the π orbitals it is deduced that the molecular π stablisation energy follows the sequence BF3 > BCl3 > (BBr3∼ Bl3), but evidence is presented that this is still consistent with the opposite sequence of π-electron delocalisation." @default.
- W2022166903 created "2016-06-24" @default.
- W2022166903 creator A5012774293 @default.
- W2022166903 creator A5035316738 @default.
- W2022166903 date "1971-01-01" @default.
- W2022166903 modified "2023-10-14" @default.
- W2022166903 title "Photoelectron spectra of halides. Part II. High-resolution spectra of the boron trihalides" @default.
- W2022166903 doi "https://doi.org/10.1039/j19710001551" @default.
- W2022166903 hasPublicationYear "1971" @default.
- W2022166903 type Work @default.
- W2022166903 sameAs 2022166903 @default.
- W2022166903 citedByCount "32" @default.
- W2022166903 countsByYear W20221669032014 @default.
- W2022166903 countsByYear W20221669032016 @default.
- W2022166903 crossrefType "journal-article" @default.
- W2022166903 hasAuthorship W2022166903A5012774293 @default.
- W2022166903 hasAuthorship W2022166903A5035316738 @default.
- W2022166903 hasConcept C121332964 @default.
- W2022166903 hasConcept C1276947 @default.
- W2022166903 hasConcept C139358910 @default.
- W2022166903 hasConcept C145148216 @default.
- W2022166903 hasConcept C147192597 @default.
- W2022166903 hasConcept C178790620 @default.
- W2022166903 hasConcept C184779094 @default.
- W2022166903 hasConcept C185592680 @default.
- W2022166903 hasConcept C198291218 @default.
- W2022166903 hasConcept C2780814088 @default.
- W2022166903 hasConcept C32909587 @default.
- W2022166903 hasConcept C4839761 @default.
- W2022166903 hasConcept C501308230 @default.
- W2022166903 hasConceptScore W2022166903C121332964 @default.
- W2022166903 hasConceptScore W2022166903C1276947 @default.
- W2022166903 hasConceptScore W2022166903C139358910 @default.
- W2022166903 hasConceptScore W2022166903C145148216 @default.
- W2022166903 hasConceptScore W2022166903C147192597 @default.
- W2022166903 hasConceptScore W2022166903C178790620 @default.
- W2022166903 hasConceptScore W2022166903C184779094 @default.
- W2022166903 hasConceptScore W2022166903C185592680 @default.
- W2022166903 hasConceptScore W2022166903C198291218 @default.
- W2022166903 hasConceptScore W2022166903C2780814088 @default.
- W2022166903 hasConceptScore W2022166903C32909587 @default.
- W2022166903 hasConceptScore W2022166903C4839761 @default.
- W2022166903 hasConceptScore W2022166903C501308230 @default.
- W2022166903 hasLocation W20221669031 @default.
- W2022166903 hasOpenAccess W2022166903 @default.
- W2022166903 hasPrimaryLocation W20221669031 @default.
- W2022166903 hasRelatedWork W1971941064 @default.
- W2022166903 hasRelatedWork W1978589905 @default.
- W2022166903 hasRelatedWork W2000813508 @default.
- W2022166903 hasRelatedWork W2011455710 @default.
- W2022166903 hasRelatedWork W2069661891 @default.
- W2022166903 hasRelatedWork W2071078824 @default.
- W2022166903 hasRelatedWork W2240393365 @default.
- W2022166903 hasRelatedWork W2317505061 @default.
- W2022166903 hasRelatedWork W2321674903 @default.
- W2022166903 hasRelatedWork W2966300259 @default.
- W2022166903 isParatext "false" @default.
- W2022166903 isRetracted "false" @default.
- W2022166903 magId "2022166903" @default.
- W2022166903 workType "article" @default.