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- W2022170705 abstract "An aryldimethylalane-appended analogue of 1,1′-bis(diphenylphosphino)ferrocene, FcPPAl, was prepared, and reaction with [Pt(nb)3] (nb=norbornene) afforded [Pt(η2-nb)(FcPPAl)] (1). Heating a solution of 1 to 80 °C resulted in crystallization of [{Pt(FcPPAl)}2] (2), whereas treatment of 1 with C2H4, C2Ph2, H2, or CO provided [PtL(FcPPAl)] [L=C2H4 (3), C2Ph2 (4)], [PtH2(FcPPAl)] (5), and [Pt(CO)(FcPPAl)] (6). In all complexes, the FcPPAl ligand is coordinated through both phosphines and the alane. Whereas 2 adopts a T-shaped geometry at platinum, 3–5 are square-pyramidal, and 6 is distorted square-planar. The hydride and carbonyl complexes feature unusual multicenter bonding involving platinum, aluminum, and a hydride or carbonyl ligand." @default.
- W2022170705 created "2016-06-24" @default.
- W2022170705 creator A5061140641 @default.
- W2022170705 creator A5075232878 @default.
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- W2022170705 date "2014-12-23" @default.
- W2022170705 modified "2023-09-27" @default.
- W2022170705 title "Synthesis and Platinum Complexes of an Alane-Appended 1,1′-Bis(phosphino)ferrocene Ligand" @default.
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- W2022170705 doi "https://doi.org/10.1002/anie.201410828" @default.
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