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- W2022171448 abstract "Homogeneous metathesis of disbustituted alkynes is performed catalytically on new O2Mo(acac)2AlEt3PhOH combinations. These systems are much more efficient than the LxMo(CO)yPhOH catalysts which require thermal activation; activities as high as 16 800 h−1 are reached at 110 °C, with entire selectivities in acetylenic hydrocarbons without isomerization. A mechanism is proposed, in which the role of phenol is to interact with the triple bond and to enhance alkyl scrambling in metallacyclobutadiene intermediates for metathesis compound production." @default.
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- W2022171448 date "1982-04-01" @default.
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- W2022171448 title "New active and selective catalysts for homogeneous metathesis of disubstituted alkynes" @default.
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- W2022171448 doi "https://doi.org/10.1016/0304-5102(82)80008-4" @default.
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