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- W2022171710 startingPage "1054" @default.
- W2022171710 abstract "The magnetic susceptibilities of bis(6-aminopurinato)copper(II) trihydrate, dichlorobis(6-aminopurine)copper (II) sesquihydrate, and dichlorobis(6-hydroxypurine)copper(II) monohydrate obey the Bleaney-Bowers equation for binuclear clusters in conformity with the results of X-ray crystal analysis. The exchange integrals within binuclear clusters were evaluated as J⁄k=−156 to −208°K. Superexchange interaction rather than the interaction of direct nature operates predominantly between copper atoms through the pπ orbitals of the heterocycles. The J⁄k values of the compounds are nearly equal to the value, −204°K, of copper(II) acetate monohydrate, although the Cu–Cu distance in the former is greater than that in the latter. The magnetic susceptibilities of dibromobis(6-aminopurine)copper(II) dihydrate, dibromobis(6-hydroxypurine)copper(II) dihydrate, dichloro(6-aminopurme)copper (II), dichloro(6-hy droxypurine)copper (II) monohydrate, and dibromo(6-hydroxypurine)copper(II) hemihydrate indicate the presence of paired copper atoms in the crystals." @default.
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- W2022171710 date "1972-04-01" @default.
- W2022171710 modified "2023-09-26" @default.
- W2022171710 title "Magnetic Properties of Copper(II) Complexes of 6-Aminopurine and 6-Hydroxypurine" @default.
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- W2022171710 doi "https://doi.org/10.1246/bcsj.45.1054" @default.
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