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- W2022172922 abstract "The photochemical behavior of UO2(C5H5N)2(NO3)2 in absolute ethanol was investigated with radiation of 254 nm, corresponding to absorption band of the coordinated pyridine. Spectrophotometric measurements were used to establish the nature and the kinetics of the photoreaction. The results show that intraligand excitations cause, in the primary photochemical act, the formation of Uo2(C5H5N)(C2H5OH)(NO3)2 complex. In addition, pyridine photolysis in a secondary photoprocess occurs, with the formation of 5-amino-2,4-pentadienal. The reaction product betweenUO2(NO3)2 and the compound formed in the photolysis of pyridine has been isolated and characterized as UO2(NO3)2(H2NCHCHCHCHO) by physico-chemical measurements." @default.
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- W2022172922 date "1974-01-01" @default.
- W2022172922 modified "2023-10-16" @default.
- W2022172922 title "Photochemical reactions of uranyl complexes. Dipyridine uranyl nitrate" @default.
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- W2022172922 doi "https://doi.org/10.1016/s0020-1693(00)89911-9" @default.
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